乙烯(12C2H4)谱带线强度的测定

G. Lebron, T. L. Tan
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引用次数: 3

摘要

从光谱分辨率为0.0063 cm−1的四个高分辨率FTIR吸光度光谱中,测量并拟合了123个属于12C2H4波段的谱线强度。使用沃森-简化哈密顿模型确定的最高状态旋转振动常数表示,用于计算带的线强度。线强度的实验拟合结果与计算结果吻合较好。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Line Intensity Measurements of the Band of Ethylene (12C2H4)
From the four high-resolution FTIR absorbance spectra recorded at a spectral resolution of 0.0063 cm−1, 123 line intensities belonging to the band of 12C2H4 were measured and fit. The upper state rovibrational constants up to sextic terms determined using a Watson's -reduced Hamiltonian model in representation were used to calculate the line intensities of the band. Results of the experimental fit of the line intensities agree well with those obtained by calculations.
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