柴油馏分萃取处理程度与优选溶剂离子液体含量的关系

M. D. Ibrahimova, S. A. Seyidova, H. J. Huseynov
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引用次数: 0

摘要

离子液体的应用前景之一是作为“绿色”优先溶剂,用于萃取油馏分中不需要的组分(芳烃、硫和树脂化合物)。各种油馏分离子液体的萃取处理工艺可以看作是一种替代性的传统处理方法和萃取工艺与其他处理方法相结合的附加方法,可以结合两种方法的优点。介绍了以醋酸二丙基和二丁胺合成的离子液体为萃取剂,对液压净化后的柴油馏分进行联合萃取处理的效果。结果表明,分步萃取柴油馏分离子液体与一步萃取相比,原油的脱芳脱硫程度较高。在用离子液体对柴油馏分液进行醋酸二诺皮铵和醋酸二丁拉铵三相萃取处理时,规定了含有较多阳离子碎片的离子液体对乙酸二诺皮铵有较高的萃取能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The dependence of degree of extraction treatment of diesel distillate from the content of preferential solvent - ionic liquid
One of the perspective directions of the employment of ionic liquids is using them as “green” preferential solvent in the process of extraction treatment of undesirable components (aromatic hydrocarbons, sulfur and resin compounds) from the composition of oil fractions. The process of extraction treatment of ionic liquid of various oil distillates may be reviewed as an alternative traditional method of treatment and additional way in the combination of extraction process with other treatment methods allowing combining the advantages of both methods. The paper presents the results of combined process of extraction treatment of hydraulically cleaned diesel fraction using as an extractant of ionic liquids synthesized based on the vinegar acid dipropyl and dibutilamines. It is shown that during step-by-step extraction treatment of ionic liquid of diesel distillate compared to the one-step process, relatively high degree of dearomatization and desulphurization of crude is achieved. In three-phase extraction treatment of diesel distillate with diropilammonium acetate and dibutillamonium acetate with ionic liquids, relatively high extraction capacity diropilammonium acetate of ionic liquids containing more voluminous cation fragment is specified.
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