Jian-Ye Ji, Xiu-Mei Li, Zhi-tao Wang, Yan-Ling Niu
{"title":"1.3.1. 基于1,3-双(咪唑-1-甲基)苯的新型三维Cd(II)配位聚合物的水热合成、晶体结构和荧光性能","authors":"Jian-Ye Ji, Xiu-Mei Li, Zhi-tao Wang, Yan-Ling Niu","doi":"10.21060/CIS.V1I3.2011","DOIUrl":null,"url":null,"abstract":"Abstract: A new cadmium(II) coordination polymer, namely[Cd(mbix)3]n·2nClO4 (mbix = 1,3-bis(imidazol-1-ylmethyl)benzene) (1), has been prepared and fully characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopyand luminescent property. Of the compound, the Cd(II)center is octahedral coordinated with mbix serving as a bridgingligand by employing six N-donor to coordinate with the Cd(II)center. It exbihits three-dimensional network structure via mbixligands.Supporting information: X-Ray (CIF file).","PeriodicalId":10648,"journal":{"name":"Communications in Inorganic Synthesis","volume":"120 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"1.3.1. Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a New Three-Dimensional Cd(II) Coordination Polymer Based on 1,3-Bis(imidazol-1- ylmethyl)-benzene\",\"authors\":\"Jian-Ye Ji, Xiu-Mei Li, Zhi-tao Wang, Yan-Ling Niu\",\"doi\":\"10.21060/CIS.V1I3.2011\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract: A new cadmium(II) coordination polymer, namely[Cd(mbix)3]n·2nClO4 (mbix = 1,3-bis(imidazol-1-ylmethyl)benzene) (1), has been prepared and fully characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopyand luminescent property. Of the compound, the Cd(II)center is octahedral coordinated with mbix serving as a bridgingligand by employing six N-donor to coordinate with the Cd(II)center. It exbihits three-dimensional network structure via mbixligands.Supporting information: X-Ray (CIF file).\",\"PeriodicalId\":10648,\"journal\":{\"name\":\"Communications in Inorganic Synthesis\",\"volume\":\"120 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Communications in Inorganic Synthesis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.21060/CIS.V1I3.2011\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Communications in Inorganic Synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.21060/CIS.V1I3.2011","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
1.3.1. Hydrothermal Synthesis, Crystal Structure and Fluorescent Property of a New Three-Dimensional Cd(II) Coordination Polymer Based on 1,3-Bis(imidazol-1- ylmethyl)-benzene
Abstract: A new cadmium(II) coordination polymer, namely[Cd(mbix)3]n·2nClO4 (mbix = 1,3-bis(imidazol-1-ylmethyl)benzene) (1), has been prepared and fully characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopyand luminescent property. Of the compound, the Cd(II)center is octahedral coordinated with mbix serving as a bridgingligand by employing six N-donor to coordinate with the Cd(II)center. It exbihits three-dimensional network structure via mbixligands.Supporting information: X-Ray (CIF file).
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