在科里奥利共振的情况下,多原子分子振动旋转能的二阶和三阶修正

S. Maes
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引用次数: 6

摘要

2014当多原子分子的振动频率发生共振时,Shaffer, Nielsen和Thomas提出的接触变换方法不能直接适用。由Nielsen,然后由Grenier-Besson, Amat和Nielsen证明,在这种情况下,变换函数应该是一个修正函数。这个问题是在科里奥利共振的情况下处理的,当旋转振动的计算问题扩展到三阶近似时。《体质杂志》第27卷,1966年,页。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Corrections du 2e et du 3e ordre à l'énergie de vibration-rotation des molécules polyatomiques dans le cas d'une résonance de coriolis
2014 When resonance between vibrational frequencies of polyatomic molecules occurs, the contact-transformation method proposed by Shaffer, Nielsen and Thomas is not directly applicable. It has been shown by Nielsen, then by Grenier-Besson, Amat and Nielsen, that in this case the transformation function should be a modified one. This problem is treated here in the case of the Coriolis resonance, when the question of the computation of the rotationvibration énergies is extended to a third order of approximation. LE JOURNAL DE PHYSIQUE TOME 27, JANYIER-FEVRIER 1966, PAGE .
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