含芳基硼酸和吡唑的硼氧辛加合物的制备、结构和热研究

H. Hassan
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引用次数: 1

摘要

四种新的硼氧合物((B3O3(Ph)3PzH) (1), (B3O3(Ph)3(PztBu,iPrH)2) (2), (B3O3(PhF2)3PzH))。用苯硼酸、3,5-二氟苯硼酸、1h -吡唑(PzH)和3-叔丁基-5-异丙基吡唑(PztBu,iPrH)2)(4)制备了PzH(3)和(B3O3(PhF2)3(PztBu,iPrH),并用元素分析、IR、1H-NMR和x射线衍射对其进行了表征。晶体学研究表明,PzH和PztBu、iPrH通过B-N负键与硼氧分子结合。它还证明了相邻分子之间不同类型的氢键相互作用。用热重分析仪考察了这些加合物的热稳定性。关键词:硼砂,晶体结构,氢键,热研究
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation, structural and thermal studies of boroxine adducts having aryl boronic acids and pyrazoles
Four new boroxine adducts ((B3O3(Ph)3PzH) (1), (B3O3(Ph)3(PztBu,iPrH)2) (2), (B3O3(PhF2)3PzH). PzH (3) and (B3O3(PhF2)3(PztBu,iPrH)2) (4)) using phenylboronic acid, 3,5-difluorophenylboronic acid, 1H-pyrazole (PzH) and 3-tert-butyl-5-isopropyl pyrazole (PztBu,iPrH) were prepared and characterized by elemental analysis, IR, 1H-NMR and X-ray diffraction. The crystallographic study reveals that PzH and PztBu,iPrH are bonded to boroxine molecule through B-N dative bond. It also demonstrates the different type of hydrogen bond interactions between adjacent molecules. The thermal stability of these adducts was investigated by TGA. Key words: Boroxine, crystal structures, hydrogen bonding, thermal study.
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