{"title":"含芳基硼酸和吡唑的硼氧辛加合物的制备、结构和热研究","authors":"H. Hassan","doi":"10.5897/AJPAC2016.0687","DOIUrl":null,"url":null,"abstract":"Four new boroxine adducts ((B3O3(Ph)3PzH) (1), (B3O3(Ph)3(PztBu,iPrH)2) (2), (B3O3(PhF2)3PzH). PzH (3) and (B3O3(PhF2)3(PztBu,iPrH)2) (4)) using phenylboronic acid, 3,5-difluorophenylboronic acid, 1H-pyrazole (PzH) and 3-tert-butyl-5-isopropyl pyrazole (PztBu,iPrH) were prepared and characterized by elemental analysis, IR, 1H-NMR and X-ray diffraction. The crystallographic study reveals that PzH and PztBu,iPrH are bonded to boroxine molecule through B-N dative bond. It also demonstrates the different type of hydrogen bond interactions between adjacent molecules. The thermal stability of these adducts was investigated by TGA. \n \n Key words: Boroxine, crystal structures, hydrogen bonding, thermal study.","PeriodicalId":7556,"journal":{"name":"African Journal of Pure and Applied Chemistry","volume":"41 1","pages":"42-55"},"PeriodicalIF":0.0000,"publicationDate":"2016-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Preparation, structural and thermal studies of boroxine adducts having aryl boronic acids and pyrazoles\",\"authors\":\"H. Hassan\",\"doi\":\"10.5897/AJPAC2016.0687\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Four new boroxine adducts ((B3O3(Ph)3PzH) (1), (B3O3(Ph)3(PztBu,iPrH)2) (2), (B3O3(PhF2)3PzH). PzH (3) and (B3O3(PhF2)3(PztBu,iPrH)2) (4)) using phenylboronic acid, 3,5-difluorophenylboronic acid, 1H-pyrazole (PzH) and 3-tert-butyl-5-isopropyl pyrazole (PztBu,iPrH) were prepared and characterized by elemental analysis, IR, 1H-NMR and X-ray diffraction. The crystallographic study reveals that PzH and PztBu,iPrH are bonded to boroxine molecule through B-N dative bond. It also demonstrates the different type of hydrogen bond interactions between adjacent molecules. The thermal stability of these adducts was investigated by TGA. \\n \\n Key words: Boroxine, crystal structures, hydrogen bonding, thermal study.\",\"PeriodicalId\":7556,\"journal\":{\"name\":\"African Journal of Pure and Applied Chemistry\",\"volume\":\"41 1\",\"pages\":\"42-55\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-08-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"African Journal of Pure and Applied Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.5897/AJPAC2016.0687\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"African Journal of Pure and Applied Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.5897/AJPAC2016.0687","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Preparation, structural and thermal studies of boroxine adducts having aryl boronic acids and pyrazoles
Four new boroxine adducts ((B3O3(Ph)3PzH) (1), (B3O3(Ph)3(PztBu,iPrH)2) (2), (B3O3(PhF2)3PzH). PzH (3) and (B3O3(PhF2)3(PztBu,iPrH)2) (4)) using phenylboronic acid, 3,5-difluorophenylboronic acid, 1H-pyrazole (PzH) and 3-tert-butyl-5-isopropyl pyrazole (PztBu,iPrH) were prepared and characterized by elemental analysis, IR, 1H-NMR and X-ray diffraction. The crystallographic study reveals that PzH and PztBu,iPrH are bonded to boroxine molecule through B-N dative bond. It also demonstrates the different type of hydrogen bond interactions between adjacent molecules. The thermal stability of these adducts was investigated by TGA.
Key words: Boroxine, crystal structures, hydrogen bonding, thermal study.