pH对苯甲酸在水-苯溶剂中溶解及其分配的影响

S. Mishra
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引用次数: 0

摘要

物质的溶解度取决于溶质-溶剂相互作用、pH、温度及其离子形式的解离等,其中溶质在两种不混溶的液体溶剂之间的分配是观察到的。本文报道了在室温(25℃)下,苯甲酸(溶质)在亲水性水和疏水性苯中的溶解度及其分配研究。用摇瓶法和滴定法分析了两种溶剂中溶质苯甲酸的分布,其平衡浓度与酸碱滴定法相同。研究了盐苯甲酸在不同pH范围(4.0、7.0和9.0)下的溶解度及其在水和苯缓冲溶液中的分配。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of pH on Benzoic Acid Solubilization and Its Partition in Water-Benzene Solvents
The solubility of substance depends on solute-solvent interaction, pH, temperature and its dissociation in ionic form etc., where the partitioning of solute between two immiscible liquid solvents is observed. Herein, we have reported the benzoic acid (solute) solubility as well as its partition study between hydrophilic water and in hydrophobic benzene, which are used as solvents at room temperature (25°C). The distribution of solute benzoic acid between these two solvents is analyzed by applying of shake-flask and titrimetric method with there equilibrium concentration as by acid-base titration method. The solubility of salt benzoic acid and their partition into water and benzene-buffer solutions have been studied at different pH range (4.0, 7.0 and 9.0) as well.
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