石蜡选择性氧化催化剂设计的关键问题

IF 9.3 2区化学 Q1 CHEMISTRY, PHYSICAL

Catalysis Reviews-Science and Engineering Pub Date : 1996-11-01 DOI:10.1080/01614949608006463

S. Albonetti, F. Cavani, F. Trifiró

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引用次数: 369

摘要

摘要本文综述了轻石蜡氧官能化多相催化剂的研究进展。特别注意了石蜡氧化脱氢制烯烃和正丁烷氧化制马来酸酐的反应。大多数催化剂组合物以氧化钒为主要成分，并讨论了该元素在催化性能方面的特殊性质。根据部分氧化产物对连续非选择性氧化反应的稳定性，以及石蜡活化的机制，这些性质也得到了检验。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Key Aspects of Catalyst Design for the Selective Oxidation of Paraffins

Abstract This review examines some aspects in the development of heterogenous catalysts for the oxyfunctionalization of light paraffins. Particular attention is devoted to the raction of paraffin oxydehydrogenation to olefins and of n-butane oxidation to maleic anhydride. Most catalyst compositions are based on vanadium oxide as the main component, and the peculiar properties of this element with respect to the catalytic performance are discussed. These properties are also examined in ligh of the stability of the product of partial oxidation towards consecutive unselective oxidation reactions, and with respect to the mechanism of paraffin activation.

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来源期刊

Catalysis Reviews-Science and Engineering 化学-物理化学

CiteScore

22.30

自引率

2.80%

发文量

期刊介绍： Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.