新型强碱性纤维阴离子交换剂的合成及性能研究

Q4 Chemistry
A. Shunkevich, A. Polikarpov, G. V. Medyak, S. D. Filippovich, Z. I. Akulich
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引用次数: 0

摘要

研究了一种新型强碱基纤维阴离子交换剂的合成方法。以聚丙烯腈纤维为原料,采用环氧氯丙烷和乙氯醇两种烷基化剂对弱碱性阴离子交换剂进行烷基化合成。研究了反应条件对新型阴离子交换剂理化性质的影响。确定了合成参数:“氨基:烷基化剂”的摩尔比、烷基化剂的浓度、反应时间和反应温度,以获得对强碱基团交换能力最大的阴离子交换剂。新型强碱性纤维具有令人满意的机械性能,可加工成各种纺织形式。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and properties of new strongly basic fibrous anion exchangers
A synthesis method of new fibrous anion exchangers with strong base groups has been developed. The synthesis was carried out by alkylation of weakly basic anion exchangers based on polyacrylonitrile fiber using two alkylating agents: epichlorohydrin and ethylene chlorohydrin. The influence of the reaction conditions on the physicochemical properties of new anion exchangers was investigated. The synthesis parameters were determined: the molar ratio of “amino groups: alkylating agent”, the concentration of the alkylating agent, the reaction time and temperature – to obtain anion exchangers with maximum exchange capacity for strong base groups. New strongly basic fibers possess satisfactory mechanical properties allowing their processing into various textile forms.
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来源期刊
CiteScore
0.30
自引率
0.00%
发文量
38
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