{"title":"强酸条件下四(五氟苯基)硼酸盐(FTPB)阴离子的合成、亲脂性和稳定性与四(3,5-二(三氟甲基)苯基)硼酸盐(TFPB)阴离子的比较","authors":"M. Isshiki, H. Kobayashi, T. Sonoda","doi":"10.15017/6671","DOIUrl":null,"url":null,"abstract":"An improved synthetic method for tetramethylammonium FTPB by a metal-halogen exchange reaction of pentafluorophenyl bromide with magnesium in the presence of a catalytic amount of butyl bromide and by a subsequent reaction with boron trifluoride diethyl ether was developed. The lipophilicity of tetramethylammonium FTPB in a range of hydrophobic organic solvents and its stability under highly acidic conditions were investigated in comparison with those of tetramethylammonium TFPB.","PeriodicalId":22886,"journal":{"name":"The reports of Institute of Advanced Material Study Kyushu University","volume":"45 1","pages":"47-55"},"PeriodicalIF":0.0000,"publicationDate":"1995-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis, Lipophilicity, and Stability of Tetrakis (pentafluorophenyl) borate (FTPB) Anion under Highly Acidic Conditions in Comparison with Those of Tetrakis (3,5-bis (trifluoromethyl) phenyl) borate (TFPB) Anion\",\"authors\":\"M. Isshiki, H. Kobayashi, T. Sonoda\",\"doi\":\"10.15017/6671\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"An improved synthetic method for tetramethylammonium FTPB by a metal-halogen exchange reaction of pentafluorophenyl bromide with magnesium in the presence of a catalytic amount of butyl bromide and by a subsequent reaction with boron trifluoride diethyl ether was developed. The lipophilicity of tetramethylammonium FTPB in a range of hydrophobic organic solvents and its stability under highly acidic conditions were investigated in comparison with those of tetramethylammonium TFPB.\",\"PeriodicalId\":22886,\"journal\":{\"name\":\"The reports of Institute of Advanced Material Study Kyushu University\",\"volume\":\"45 1\",\"pages\":\"47-55\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The reports of Institute of Advanced Material Study Kyushu University\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15017/6671\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The reports of Institute of Advanced Material Study Kyushu University","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15017/6671","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis, Lipophilicity, and Stability of Tetrakis (pentafluorophenyl) borate (FTPB) Anion under Highly Acidic Conditions in Comparison with Those of Tetrakis (3,5-bis (trifluoromethyl) phenyl) borate (TFPB) Anion
An improved synthetic method for tetramethylammonium FTPB by a metal-halogen exchange reaction of pentafluorophenyl bromide with magnesium in the presence of a catalytic amount of butyl bromide and by a subsequent reaction with boron trifluoride diethyl ether was developed. The lipophilicity of tetramethylammonium FTPB in a range of hydrophobic organic solvents and its stability under highly acidic conditions were investigated in comparison with those of tetramethylammonium TFPB.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
