{"title":"磷基烯的新加成和环化反应","authors":"K. Swamy, M. Pavan, M. Anitha, G. Gangadhararao","doi":"10.1080/10426507.2017.1417302","DOIUrl":null,"url":null,"abstract":"GRAPHICAL ABSTRACT ABSTRACT In this paper, we describe convenient methods for functionally active phenol addition reaction of allenylphosphonates/allenyl phosphine oxides. These reactions lead to either vinyl or allylphosphonates. In the reaction α-aryl allenylphosphonates with 2-iodophenol in the presence of Pd nanoparticles [Pd-PVP] isomeric vinylphosphonates are preferentially obtained. A novel cyclization reaction of 2-iodo-t-butylbenzaldimine with and allenylphosphine oxide that leads to an isoquinoline is also discovered; the product is characterized by single crystal X-ray structure determination.","PeriodicalId":20043,"journal":{"name":"Phosphorus Sulfur and Silicon and The Related Elements","volume":"94 1","pages":"81 - 87"},"PeriodicalIF":0.0000,"publicationDate":"2018-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"New addition and cyclization reactions involving phosphorus based allenes\",\"authors\":\"K. Swamy, M. Pavan, M. Anitha, G. Gangadhararao\",\"doi\":\"10.1080/10426507.2017.1417302\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"GRAPHICAL ABSTRACT ABSTRACT In this paper, we describe convenient methods for functionally active phenol addition reaction of allenylphosphonates/allenyl phosphine oxides. These reactions lead to either vinyl or allylphosphonates. In the reaction α-aryl allenylphosphonates with 2-iodophenol in the presence of Pd nanoparticles [Pd-PVP] isomeric vinylphosphonates are preferentially obtained. A novel cyclization reaction of 2-iodo-t-butylbenzaldimine with and allenylphosphine oxide that leads to an isoquinoline is also discovered; the product is characterized by single crystal X-ray structure determination.\",\"PeriodicalId\":20043,\"journal\":{\"name\":\"Phosphorus Sulfur and Silicon and The Related Elements\",\"volume\":\"94 1\",\"pages\":\"81 - 87\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-01-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus Sulfur and Silicon and The Related Elements\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/10426507.2017.1417302\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus Sulfur and Silicon and The Related Elements","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/10426507.2017.1417302","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
New addition and cyclization reactions involving phosphorus based allenes
GRAPHICAL ABSTRACT ABSTRACT In this paper, we describe convenient methods for functionally active phenol addition reaction of allenylphosphonates/allenyl phosphine oxides. These reactions lead to either vinyl or allylphosphonates. In the reaction α-aryl allenylphosphonates with 2-iodophenol in the presence of Pd nanoparticles [Pd-PVP] isomeric vinylphosphonates are preferentially obtained. A novel cyclization reaction of 2-iodo-t-butylbenzaldimine with and allenylphosphine oxide that leads to an isoquinoline is also discovered; the product is characterized by single crystal X-ray structure determination.
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