打开工具箱:混合气体吸附测量的18种实验技术

M. Bülow
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引用次数: 21

摘要

吸附分离系统提供了用更高效的过程取代或增强传统分离系统的可能性,从而极大地节省了能源。然而,与蒸馏或吸收塔相比,吸附系统在过程模拟软件中不容易评估尽可能多的单元操作。缺乏预测气体混合物吸附的能力是阻碍吸附分离实施的一个持久障碍。尽管现有的测量混合气体吸附的方法种类繁多,但这种缺点是由于测量气体混合物吸附的能力同样持续不足造成的。这项工作介绍了18种用于测量混合物吸附的技术的全面概述,包括每种方法中使用的设备和原理以及每种技术的优点和缺点。这项工作还提供了建议,哪些方法可能最适合测量混合物吸附感兴趣的实验者的个人需要,并包括对混合物吸附测量的未来展望。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Opening the Toolbox: 18 Experimental Techniques for Measurement of Mixed Gas Adsorption
: Adsorption separation systems o ff er the possibility to replace or augment legacy separation systems with more e ffi cient processes, resulting in enormous savings in energy. However, adsorption systems are not as easily evaluated as possible unit operations in process simulation software compared to distillation or absorption columns. The lack of ability to predict adsorption of gas mixtures represents a persistent barrier holding back implementation of adsorption separations. This shortcoming is the result of an equally persistent de fi ciency in the ability to measure adsorption of gas mixtures, despite the huge variety of existing methods to measure mixture adsorption. This work presents a comprehensive overview of 18 techniques used to measure mixture adsorption, including the equipment and principles used in each method as well as the strengths and shortcomings of each technique. This work also provides recommendations for which methods may best suit the individual needs of experimentalists interested in measuring mixture adsorption and includes an outlook on the future of mixture adsorption measurement.
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