{"title":"烷基格氏试剂催化二氯化钛加氢镁化炔烃的机理研究","authors":"Yuan Gao, F. Sato","doi":"10.1039/C39950000659","DOIUrl":null,"url":null,"abstract":"The mechanism of titanocenedichloride-catalysed hydromagnesiation reaction of alkynes with an alkyl Grignard reagent is elucidated and it is revealed that the regiochemistry of the reaction controlled at the step of transmetallation from titanium to magnesium.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"69 1","pages":"659-660"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"32","resultStr":"{\"title\":\"On the mechanism of titanocenedichloride-catalysed hydromagnesiation of alkynes with alkyl Grignard reagents\",\"authors\":\"Yuan Gao, F. Sato\",\"doi\":\"10.1039/C39950000659\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The mechanism of titanocenedichloride-catalysed hydromagnesiation reaction of alkynes with an alkyl Grignard reagent is elucidated and it is revealed that the regiochemistry of the reaction controlled at the step of transmetallation from titanium to magnesium.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":\"69 1\",\"pages\":\"659-660\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"32\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950000659\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950000659","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
On the mechanism of titanocenedichloride-catalysed hydromagnesiation of alkynes with alkyl Grignard reagents
The mechanism of titanocenedichloride-catalysed hydromagnesiation reaction of alkynes with an alkyl Grignard reagent is elucidated and it is revealed that the regiochemistry of the reaction controlled at the step of transmetallation from titanium to magnesium.
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