{"title":"以无催化剂和原子经济性的[4+3]环加成法将偶氮二烯与环偶氮亚胺轻松合成 1,2,4-三氮杂卓","authors":"Lesong Li , Tao Liu , Weiwu Ren , Yang Wang","doi":"10.1016/j.gresc.2022.10.010","DOIUrl":null,"url":null,"abstract":"<div><p>A catalyst-free and atom-economical [4 + 3] cycloaddition of azadienes with <em>C</em>,<em>N</em>-cyclic azomethine imines has been developed, providing an efficient and environmentally benign access to 1,2,4-triazepines with high diastereoselectivities and yields. This reaction can be performed in 2-methyltetrahydrofuran under mild conditions smoothly.</p></div>","PeriodicalId":12794,"journal":{"name":"Green Synthesis and Catalysis","volume":"5 1","pages":"Pages 57-61"},"PeriodicalIF":0.0000,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666554922001090/pdfft?md5=35bfc7b8c13710d438eb5df294da0ef1&pid=1-s2.0-S2666554922001090-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Catalyst-free and atom-economical [4+3] cycloaddition of azadienes with cyclic azomethine imines for facile synthesis of 1,2,4-triazepines\",\"authors\":\"Lesong Li , Tao Liu , Weiwu Ren , Yang Wang\",\"doi\":\"10.1016/j.gresc.2022.10.010\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A catalyst-free and atom-economical [4 + 3] cycloaddition of azadienes with <em>C</em>,<em>N</em>-cyclic azomethine imines has been developed, providing an efficient and environmentally benign access to 1,2,4-triazepines with high diastereoselectivities and yields. This reaction can be performed in 2-methyltetrahydrofuran under mild conditions smoothly.</p></div>\",\"PeriodicalId\":12794,\"journal\":{\"name\":\"Green Synthesis and Catalysis\",\"volume\":\"5 1\",\"pages\":\"Pages 57-61\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2666554922001090/pdfft?md5=35bfc7b8c13710d438eb5df294da0ef1&pid=1-s2.0-S2666554922001090-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green Synthesis and Catalysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666554922001090\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green Synthesis and Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666554922001090","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Catalyst-free and atom-economical [4+3] cycloaddition of azadienes with cyclic azomethine imines for facile synthesis of 1,2,4-triazepines
A catalyst-free and atom-economical [4 + 3] cycloaddition of azadienes with C,N-cyclic azomethine imines has been developed, providing an efficient and environmentally benign access to 1,2,4-triazepines with high diastereoselectivities and yields. This reaction can be performed in 2-methyltetrahydrofuran under mild conditions smoothly.
![Catalyst-free and atom-economical [4+3] cycloaddition of azadienes with cyclic azomethine imines for facile synthesis of 1,2,4-triazepines](https://img.booksci.cn/booksciimg/2024-2/96287452041737794872.jpg)
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