类黄酮苷结构表征的串联质谱策略

F. Cuyckens, Y. Ma, G. Pocsfalvi, M. Claeys
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引用次数: 107

摘要

本文综述了用串联质谱方法研究植物次生代谢产物黄酮类苷的结构特征。它演示了如何从(i)碳酸酯序列,(ii)苷元部分和(iii)二糖苷部分的连接上获得o -二糖苷的结构信息。正离子模式和负离子模式都被采用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Tandem mass spectral strategies for the structural characterization of flavonoid glycosides
In this article we review tandem mass spectral approaches to the structural characterization of flavonoid glycosides wich are ubiquitous secondary plant metabolites. It is demonstrated how structural information on O-diglycosides can be obtained on (i) the carboydrate sequence, (ii) the aglycone part, and (iii) the linkage in the diglycosidic part. Both the positive and negative ion modes have been employed.
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