基于磷酸盐衍生物的新型阻燃剂

M. L. Yeritsyan, Armen M. Arustamyan, I. N. Sirekanyan, Lena G. Mkoyan, Lilit Stepanyan
{"title":"基于磷酸盐衍生物的新型阻燃剂","authors":"M. L. Yeritsyan, Armen M. Arustamyan, I. N. Sirekanyan, Lena G. Mkoyan, Lilit Stepanyan","doi":"10.46991/pysu:b/2022.56.2.131","DOIUrl":null,"url":null,"abstract":"One of the main problems of nature conservation and protection of the environ-ment is the reducing of flammability of natural and synthetic materials as well as products based on them. In order to obtain non-combustible materials such as flame retardants, monosodium salt of orthophosphoric acid, urea, thiourea and their mono-methylol derivatives, as well as N-monomethylol acrylamide were used in this work. The reaction for the synthesis of the mentioned compounds was carried out in the presence of a small amount of water. During the reaction between urea and monosodium salt of orthophosphoric acid, ammonia and СО2 were released. In the case of the reaction of thiocarbamide with the monosodium salt of orthophosphoric acid, in addition to ammonia and CO2, hydrogen sulfide is partially released, the formation mechanism of which is presented in the work.","PeriodicalId":20692,"journal":{"name":"Proceedings of the YSU B: Chemical and Biological Sciences","volume":"33 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2022-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"NEW TYPES OF FLAME RETARDANTS BASED ON PHOSPHATE DERIVATIVES\",\"authors\":\"M. L. Yeritsyan, Armen M. Arustamyan, I. N. Sirekanyan, Lena G. Mkoyan, Lilit Stepanyan\",\"doi\":\"10.46991/pysu:b/2022.56.2.131\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"One of the main problems of nature conservation and protection of the environ-ment is the reducing of flammability of natural and synthetic materials as well as products based on them. In order to obtain non-combustible materials such as flame retardants, monosodium salt of orthophosphoric acid, urea, thiourea and their mono-methylol derivatives, as well as N-monomethylol acrylamide were used in this work. The reaction for the synthesis of the mentioned compounds was carried out in the presence of a small amount of water. During the reaction between urea and monosodium salt of orthophosphoric acid, ammonia and СО2 were released. In the case of the reaction of thiocarbamide with the monosodium salt of orthophosphoric acid, in addition to ammonia and CO2, hydrogen sulfide is partially released, the formation mechanism of which is presented in the work.\",\"PeriodicalId\":20692,\"journal\":{\"name\":\"Proceedings of the YSU B: Chemical and Biological Sciences\",\"volume\":\"33 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-06-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings of the YSU B: Chemical and Biological Sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.46991/pysu:b/2022.56.2.131\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of the YSU B: Chemical and Biological Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.46991/pysu:b/2022.56.2.131","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

降低天然材料和合成材料及其制品的可燃性是自然保护和环境保护的主要问题之一。为了获得阻燃剂等不燃材料,本工作中使用了正磷酸钠盐、尿素、硫脲及其单甲基衍生物以及n-单甲基丙烯酰胺。上述化合物的合成反应是在少量水的存在下进行的。尿素与正磷酸单钠盐反应时,释放出氨和СО2。硫代氨基脲与正磷酸单钠盐反应时,除氨和CO2外,还部分释放出硫化氢,本文介绍了硫化氢的形成机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
NEW TYPES OF FLAME RETARDANTS BASED ON PHOSPHATE DERIVATIVES
One of the main problems of nature conservation and protection of the environ-ment is the reducing of flammability of natural and synthetic materials as well as products based on them. In order to obtain non-combustible materials such as flame retardants, monosodium salt of orthophosphoric acid, urea, thiourea and their mono-methylol derivatives, as well as N-monomethylol acrylamide were used in this work. The reaction for the synthesis of the mentioned compounds was carried out in the presence of a small amount of water. During the reaction between urea and monosodium salt of orthophosphoric acid, ammonia and СО2 were released. In the case of the reaction of thiocarbamide with the monosodium salt of orthophosphoric acid, in addition to ammonia and CO2, hydrogen sulfide is partially released, the formation mechanism of which is presented in the work.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信