水热碳化香蕉皮对重金属吸附的初始离子效应

Nurhaliza Said Mohd, R. Mohamed
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引用次数: 8

摘要

重金属在水中的积累尤其重要,因为它可能通过污染食物对人体健康产生影响。对香蕉皮的使用进行了研究。选择水热碳化(HTC)作为替代工艺。本课题的目的是通过HTC法合成香蕉皮碳氢化合物吸附剂,并评价香蕉皮碳氢化合物吸附剂对重金属的吸附性能。传统的重金属去除方法操作成本高,需要高技能的工人,并且在操作结束时产生污泥。与其他技术相比,香蕉皮吸附剂具有成本效益高、操作简单、环境安全、对操作人员无健康风险等优点。此外,大量的香蕉皮废弃物造成了严重的处理问题。因此,本研究通过水热碳化法制备香蕉皮吸附剂,有望解决香蕉皮的问题。本项目分为三个阶段,第一阶段是基于碳氢化合物的香蕉皮合成,香蕉皮被切碎成小块。然后将其在KOH溶液中浸泡2h,然后将其转移到聚四氟乙烯中,在230℃下加热2h。第二阶段,利用FTIR对香蕉皮烃类进行理化表征。结果表明,香蕉皮中的所有物质都能活化香蕉皮表面,增强香蕉皮对重金属的吸附。在最后阶段,采用原子吸收光谱法测定了金属的初始浓度和终浓度,以确定所制备的烃类对重金属的去除率。结果表明,随着初始金属浓度的增加,水合物的脱除能力增大。研究表明,金属的初始浓度越高,烃类对金属的去除能力也越高、越强。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
THE INITIAL ION EFFECT OF HEAVY METALS ADSORPTION BY USING HYDROTHERMAL CARBONIZATION BANANA PEELS
Accumulation of heavy metals in water is of particularly important because it can impact upon human health through possible contamination of food. The use of banana peel was investigated. Hydrothermal carbonization (HTC) was chosen as alternative process. The objective of this project is to synthesize banana peel hydrochars adsorbent via HTC process and to evaluate the heavy metals adsorption performance of banana peel hydrochars adsorbent. Conventional methods in removal of heavy metals require high operational cost, need highly skilled labour, and generate sludge at the end of the operation. Compared to other techniques, banana peel absorbent is a cost- effective adsorbent, easy to operate, environmentally safe and no health risk for the operator. Besides, large quantity of banana peel waste contributes to its significant disposal problem. Thus, this study is expected to solve problems of banana peel, by preparing banana peel adsorbent through hydrothermal carbonization. There are three phases in this project, phase 1 which is synthesis of banana peel based on hydrochars, banana peel was chopped the peels into small pieces. It was then soaked in KOH solution for 2hours and transferred into PTFE and heat for 2hours at 230°C. For phase 2, physico-chemical characterization of banana peels hydrochars by using FTIR. The result obtained shown that all of the content in banana peels will activate the surface of banana peel to enhance the adsorption of the heavy metals. For the final phase, by using AAS, the initial and final concentration of the metals was tested to determine the removal of heavy metals by the prepared hydrochars. The results showed that the removal capacity of the hydrochars increased when the initial concentration of the metals increased. From the research, it can be concluded that, as the initial concentration of the metals higher, the ability of the hydrochars to remove the metals also higher and stronger.
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