pr2cuo4纤维静电纺丝及其在固体氧化物燃料电池中的阴极应用

T. Chiu, Chien-Hung Chen, Heng-Yi Shih, H. Chang, Yao-Ming Wang, S. Sakthinathan
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引用次数: 1

摘要

在本研究中,制备了Pr2CuO4作为中温固体氧化物燃料电池(IT-SOFCs)的正极材料。采用固相反应和静电纺丝技术制备了Pr2CuO4阴极。采用合适的表征技术对制备的正极材料进行了表征。将Pr2CuO4包覆在Sm0.2Ce0.8O1.9 (SDC20)微球上,形成半电池(Ag/Pr2CuO4/SDC20/Ag)。静电纺丝法制备的Pr2CuO4阴极在电化学测量中表现出优异的阴极性能。阴极的纤维形态诱导了大量的三相界面,促进了氧在表面的扩散。在800°C空气中,Pr2CuO4纤维获得的最低面积比电阻为0.35 Ω cm2。静电纺丝制备的Pr2CuO4纤维是一种很有潜力的it - sofc正极材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrospinning of Pr 2 CuO 4 Fiber and its Cathode Application in Solid Oxide Fuel Cell
In this study, Pr2CuO4 was fabricated as a cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs) application. The Pr2CuO4 cathode was prepared using a solid-state reaction and an electrospinning technique. The prepared cathode material was characterized by the suitable characterization technique. The Pr2CuO4 was coated on a Sm0.2Ce0.8O1.9 (SDC20) pellet with a doctor blades to form a half-cell (Ag/Pr2CuO4/SDC20/Ag). The Pr2CuO4 cathode prepared using electrospinning method demonstrated an excellent cathode performance in electrochemical measurements. The fiber morphologies of the cathode induced large amounts of triple phase boundaries, which promoted oxygen diffusion on the surface. The lowest area-specific resistance obtained with the Pr2CuO4 fiber was determined to be 0.35 Ω cm2 at 800°C in air. The electrospinning prepared Pr2CuO4 fiber is a potential cathode material for IT-SOFCs.
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