{"title":"一种新型肟配体的合成及其与金属离子配合物的表征与研究","authors":"E. Taş, M. Ulusoy, M. Guler","doi":"10.1081/SIM-120039267","DOIUrl":null,"url":null,"abstract":"Abstract A novel dioxime, 1,2‐dihydroxyimino‐3‐aza‐6‐morpholine heptane (H2L) was synthesized by the reaction of anti‐monochloroglyoxime and 4‐(3‐aminopropyl)morpholine in absolute THF. Mononuclear complexes with a metal:ligand ratio of 1:2 were prepared with Co(II), Cu(II), and Ni(II). The ligand and complexes were characterized by elemental analyses, FT‐IR, UV‐Vis, 1H NMR and 13C NMR spectra, magnetic susceptibility measurements. The thermal behavior of the compounds has been studied by thermogravimetry (TGA).","PeriodicalId":22160,"journal":{"name":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","volume":"10 1","pages":"1211 - 1221"},"PeriodicalIF":0.0000,"publicationDate":"2004-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"10","resultStr":"{\"title\":\"Synthesis of a Novel Oxime Ligand: Characterization and Investigation of Its Complexes with Some Metal Ions\",\"authors\":\"E. Taş, M. Ulusoy, M. Guler\",\"doi\":\"10.1081/SIM-120039267\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract A novel dioxime, 1,2‐dihydroxyimino‐3‐aza‐6‐morpholine heptane (H2L) was synthesized by the reaction of anti‐monochloroglyoxime and 4‐(3‐aminopropyl)morpholine in absolute THF. Mononuclear complexes with a metal:ligand ratio of 1:2 were prepared with Co(II), Cu(II), and Ni(II). The ligand and complexes were characterized by elemental analyses, FT‐IR, UV‐Vis, 1H NMR and 13C NMR spectra, magnetic susceptibility measurements. The thermal behavior of the compounds has been studied by thermogravimetry (TGA).\",\"PeriodicalId\":22160,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"volume\":\"10 1\",\"pages\":\"1211 - 1221\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/SIM-120039267\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/SIM-120039267","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Synthesis of a Novel Oxime Ligand: Characterization and Investigation of Its Complexes with Some Metal Ions
Abstract A novel dioxime, 1,2‐dihydroxyimino‐3‐aza‐6‐morpholine heptane (H2L) was synthesized by the reaction of anti‐monochloroglyoxime and 4‐(3‐aminopropyl)morpholine in absolute THF. Mononuclear complexes with a metal:ligand ratio of 1:2 were prepared with Co(II), Cu(II), and Ni(II). The ligand and complexes were characterized by elemental analyses, FT‐IR, UV‐Vis, 1H NMR and 13C NMR spectra, magnetic susceptibility measurements. The thermal behavior of the compounds has been studied by thermogravimetry (TGA).
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