{"title":"三氯化砷三甲胺、AsCl3、NMe3的晶体结构","authors":"M. Webster, S. Keats","doi":"10.1039/J19710000836","DOIUrl":null,"url":null,"abstract":"The title compound has been examined by single-crystal X-ray diffraction and crystallises in the space group P21/c with Z= 4 in a unit cell of dimensions a= 6·14, b= 10·33, c= 14·85 A, and β= 107·0°. The structure consists of discrete AsCl3,NMe3 molecules which may be considered to be based on trigonal bipyramidal arsenic co-ordination and the photographically estimated three-dimensional data were refined to R 0·083.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"63 1","pages":"836-838"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"Crystal structure of arsenic trichloride–trimethylamine, AsCl3,NMe3\",\"authors\":\"M. Webster, S. Keats\",\"doi\":\"10.1039/J19710000836\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The title compound has been examined by single-crystal X-ray diffraction and crystallises in the space group P21/c with Z= 4 in a unit cell of dimensions a= 6·14, b= 10·33, c= 14·85 A, and β= 107·0°. The structure consists of discrete AsCl3,NMe3 molecules which may be considered to be based on trigonal bipyramidal arsenic co-ordination and the photographically estimated three-dimensional data were refined to R 0·083.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":\"63 1\",\"pages\":\"836-838\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710000836\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000836","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Crystal structure of arsenic trichloride–trimethylamine, AsCl3,NMe3
The title compound has been examined by single-crystal X-ray diffraction and crystallises in the space group P21/c with Z= 4 in a unit cell of dimensions a= 6·14, b= 10·33, c= 14·85 A, and β= 107·0°. The structure consists of discrete AsCl3,NMe3 molecules which may be considered to be based on trigonal bipyramidal arsenic co-ordination and the photographically estimated three-dimensional data were refined to R 0·083.
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