{"title":"Kesan bahan penyokong terhadap aktiviti pemangkin nano ruthenium dalam hidrogenolisis gliserol","authors":"Noraini Hamzah, Mohd Ambar Yarmo","doi":"10.17576/MJAS-2016-2002-24","DOIUrl":null,"url":null,"abstract":"A series of heterogenous catalysts based on supported ruthenium were prepared from RuCl3 precusor by impregnation method. The effect of support materials (bentonite, TiO2, Al2O3 and SiO2) on catalytic activity of Ru catalyst for hydrogenolysis of glycerol were investigated under mild reaction condition of 150C and 20 bar initial hydrogen pressure for 7 hours reaction time and glycerol concentration was 20%(wt). It was found that the type of support material have significant effects on the activity and selectivity of glycerol hydrogenolysis. The order of Ru catalyst activity was Ru/bentonite > Ru/Al2O3 Ru/TiO2 > Ru/SiO2. This study showed that bentonite supported Ru catalyst was the most active with glycerol conversion reaching 62.5% compared to other supports. All the tested catalyst exhibited high selectivity to 1,2-propanediol with more than 80%. Characterization of the catalysts was carried out using BET, XPS, FESEM-EDX and TEM to obtain the physicochemical properties of the catalysts.","PeriodicalId":22844,"journal":{"name":"The Malaysian Journal of Analytical Sciences","volume":"3 1","pages":"393-400"},"PeriodicalIF":0.0000,"publicationDate":"2016-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Malaysian Journal of Analytical Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17576/MJAS-2016-2002-24","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Kesan bahan penyokong terhadap aktiviti pemangkin nano ruthenium dalam hidrogenolisis gliserol
A series of heterogenous catalysts based on supported ruthenium were prepared from RuCl3 precusor by impregnation method. The effect of support materials (bentonite, TiO2, Al2O3 and SiO2) on catalytic activity of Ru catalyst for hydrogenolysis of glycerol were investigated under mild reaction condition of 150C and 20 bar initial hydrogen pressure for 7 hours reaction time and glycerol concentration was 20%(wt). It was found that the type of support material have significant effects on the activity and selectivity of glycerol hydrogenolysis. The order of Ru catalyst activity was Ru/bentonite > Ru/Al2O3 Ru/TiO2 > Ru/SiO2. This study showed that bentonite supported Ru catalyst was the most active with glycerol conversion reaching 62.5% compared to other supports. All the tested catalyst exhibited high selectivity to 1,2-propanediol with more than 80%. Characterization of the catalysts was carried out using BET, XPS, FESEM-EDX and TEM to obtain the physicochemical properties of the catalysts.
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