K2O-P2O5-Fe2O3-MIIO-MoO3助熔剂体系的相形成

2012 IEEE International Conference on Oxide Materials for Electronic Engineering (OMEE) Pub Date : 2012-09-01 DOI:10.1109/OMEE.2012.6464778

M. Yatskin, I. Zatovsky, N. Strutynska, V. Baumer, N. Slobodyanik

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引用次数: 0

摘要

KMg0.09Fe1.91(PO4)2与KMIIFe(PO4)2 (MII - Fe, Cu)(单斜系，空间群P 21/n)呈同型。该框架由[FeO5]和[Fe(Mg)O6]多面体组成，共享顶点和边缘，并由两种桥接PO4四面体连接。K原子是九配位的，位于沿c轴方向的六边形通道中。

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Phase formation in the flux systems K2O-P2O5-Fe2O3-MIIO-MoO3

KMg0.09Fe1.91(PO4)2 is isotypic with KM^IIFe(PO4)2 (M^II - Fe, Cu) (monoclinic system, space group P 21/n). The framework is built up from [FeO5] and [Fe(Mg)O6] polyhedra sharing vertices, edges and connected by two types of bridging PO4 tetrahedra. The K atoms are nine-coordinated and are located in hexagonal channels running along the direction of c-axis.

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2012 IEEE International Conference on Oxide Materials for Electronic Engineering (OMEE)

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