{"title":"正戊烷在第八族金属/氢分子筛Y催化剂上的异构化","authors":"M. Saito, Takahisa Iwasaki","doi":"10.1627/jpi1959.19.30","DOIUrl":null,"url":null,"abstract":"duced into the zeolite by ion-exchanging it with an aqueous solution containing the metal ion. Isomerization activity leveled off to a maximum at some metal content, whereas that of hydrogenolysis increased with increasing metal content with the exception of Pd/HY. The order of maximum isomerization activities of the catalysts was as follows: Pt/HY>Pd/HY, Rh/HY>Ir/HY>Ni/HY>Co/HY>Ru/HY>Fe/HY The order of hydrogenolysis activities was as follows: Ru/HY>Rh/HY>Ir/HY>Pt/HY>Pd/HY; Co/HY> Ni/HY>Fe/HY From these results, Pd/HY and Pt/HY were found to be the most active and selective among Group VIII metal/HY catalysts for isomerization of n-pentane to isopentane. Finally, the mechanism of isomerization of n-pentane was discussed on the basis of the present experimental results.","PeriodicalId":9596,"journal":{"name":"Bulletin of The Japan Petroleum Institute","volume":"13 1","pages":"30-36"},"PeriodicalIF":0.0000,"publicationDate":"1977-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Isomerization of n-Pentane on Group VIII Metal/Hydrogen-Zeolite Y Catalysts\",\"authors\":\"M. Saito, Takahisa Iwasaki\",\"doi\":\"10.1627/jpi1959.19.30\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"duced into the zeolite by ion-exchanging it with an aqueous solution containing the metal ion. Isomerization activity leveled off to a maximum at some metal content, whereas that of hydrogenolysis increased with increasing metal content with the exception of Pd/HY. The order of maximum isomerization activities of the catalysts was as follows: Pt/HY>Pd/HY, Rh/HY>Ir/HY>Ni/HY>Co/HY>Ru/HY>Fe/HY The order of hydrogenolysis activities was as follows: Ru/HY>Rh/HY>Ir/HY>Pt/HY>Pd/HY; Co/HY> Ni/HY>Fe/HY From these results, Pd/HY and Pt/HY were found to be the most active and selective among Group VIII metal/HY catalysts for isomerization of n-pentane to isopentane. Finally, the mechanism of isomerization of n-pentane was discussed on the basis of the present experimental results.\",\"PeriodicalId\":9596,\"journal\":{\"name\":\"Bulletin of The Japan Petroleum Institute\",\"volume\":\"13 1\",\"pages\":\"30-36\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1977-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bulletin of The Japan Petroleum Institute\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1627/jpi1959.19.30\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of The Japan Petroleum Institute","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1627/jpi1959.19.30","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Isomerization of n-Pentane on Group VIII Metal/Hydrogen-Zeolite Y Catalysts
duced into the zeolite by ion-exchanging it with an aqueous solution containing the metal ion. Isomerization activity leveled off to a maximum at some metal content, whereas that of hydrogenolysis increased with increasing metal content with the exception of Pd/HY. The order of maximum isomerization activities of the catalysts was as follows: Pt/HY>Pd/HY, Rh/HY>Ir/HY>Ni/HY>Co/HY>Ru/HY>Fe/HY The order of hydrogenolysis activities was as follows: Ru/HY>Rh/HY>Ir/HY>Pt/HY>Pd/HY; Co/HY> Ni/HY>Fe/HY From these results, Pd/HY and Pt/HY were found to be the most active and selective among Group VIII metal/HY catalysts for isomerization of n-pentane to isopentane. Finally, the mechanism of isomerization of n-pentane was discussed on the basis of the present experimental results.
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