{"title":"磷酸六氢镍(II)铵的晶体结构","authors":"R. Blachnik, T. Wiest, A. Diilmer, H. Reuter","doi":"10.1524/ZKRI.1997.212.1.20","DOIUrl":null,"url":null,"abstract":"The crystal structure of ammonium hexaaqua-nickel(II) phosphate [Ni(H 2 O) 6 ][NH 4 ][PO 4 ] was determined by single crystal X-ray methods. The compound crystallizes with orthorhombic symmetry in the space group Pmn2 1 with cell parameters of a = 692.40(14) pm, b = 610.40(12) pm, c=1116.6(2)pm, Z = 2. The cell contains two nickel(II) cations, octahedrally coordinated by six H 2 O molecules, two NH4 + cations and two phosphate anions, all connected by hydrogen bonds.","PeriodicalId":23855,"journal":{"name":"Zeitschrift für Kristallographie - Crystalline Materials","volume":"54 1","pages":"20 - 23"},"PeriodicalIF":0.0000,"publicationDate":"1997-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"14","resultStr":"{\"title\":\"The crystal structure of ammonium hexaaquanickel(II) phosphate\",\"authors\":\"R. Blachnik, T. Wiest, A. Diilmer, H. Reuter\",\"doi\":\"10.1524/ZKRI.1997.212.1.20\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The crystal structure of ammonium hexaaqua-nickel(II) phosphate [Ni(H 2 O) 6 ][NH 4 ][PO 4 ] was determined by single crystal X-ray methods. The compound crystallizes with orthorhombic symmetry in the space group Pmn2 1 with cell parameters of a = 692.40(14) pm, b = 610.40(12) pm, c=1116.6(2)pm, Z = 2. The cell contains two nickel(II) cations, octahedrally coordinated by six H 2 O molecules, two NH4 + cations and two phosphate anions, all connected by hydrogen bonds.\",\"PeriodicalId\":23855,\"journal\":{\"name\":\"Zeitschrift für Kristallographie - Crystalline Materials\",\"volume\":\"54 1\",\"pages\":\"20 - 23\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1997-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"14\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift für Kristallographie - Crystalline Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1524/ZKRI.1997.212.1.20\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für Kristallographie - Crystalline Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1524/ZKRI.1997.212.1.20","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 14
摘要
用单晶x射线法测定了磷酸六水镍铵[Ni(h2o) 6][nh4][po4]的晶体结构。该化合物在Pmn2 - 1空间群中具有正交对称结晶，晶胞参数为a = 692.40(14) pm, b = 610.40(12) pm, c=1116.6(2)pm, Z = 2。该电池包含两个镍(II)阳离子，由六个h2o分子八面体配位，两个NH4 +阳离子和两个磷酸阴离子，它们都通过氢键连接。
The crystal structure of ammonium hexaaquanickel(II) phosphate
The crystal structure of ammonium hexaaqua-nickel(II) phosphate [Ni(H 2 O) 6 ][NH 4 ][PO 4 ] was determined by single crystal X-ray methods. The compound crystallizes with orthorhombic symmetry in the space group Pmn2 1 with cell parameters of a = 692.40(14) pm, b = 610.40(12) pm, c=1116.6(2)pm, Z = 2. The cell contains two nickel(II) cations, octahedrally coordinated by six H 2 O molecules, two NH4 + cations and two phosphate anions, all connected by hydrogen bonds.
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