2,2′-双喹啉多核银配合物的合成与光谱表征

D. Gurešić, Sonja Ž. Đurić, Tina P. Andrejević, Mirjana Popsavin, Biljana Đ. Glišić
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引用次数: 1

摘要

以等摩尔量的硝酸银(I)与2,2′-双喹啉(2,2′-bq)在乙醇中室温反应合成了多核银(I)配合物[Ag(NO3-O)(2,2′-bq,N′)]N。通过元素微量分析、红外光谱、核磁共振(H和C)和紫外可见光谱技术对配合物进行了表征。光谱分析结果表明,在[Ag(NO3-O)(2,2 ' -bq-N,N ')] N配合物中,2,2 ' -bq配体表现为螯合体,其余配位由两个硝酸盐的氧原子占据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and spectroscopic characterization of polynuclear silver(I) complex with 2,2'-biquinoline
Polynuclear silver(I) complex, [Ag(NO3-O)(2,2’-bq-N,N’)]n, was synthesized by the reaction of equimolar amount of silver(I) nitrate and 2,2’-biquinoline (2,2’-bq) in ethanol at room temperature. The characterization of the complex was established on the basis of elemental microanalysis, IR, NMR (H and C) and UV-Vis spectroscopic techniques. The results of spectroscopic analyses revealed that in [Ag(NO3-O)(2,2’-bq-N,N’)]n complex, 2,2’-bq ligand behaves as a chelate, while the remaining coordination sites are occupied by the oxygen atoms of two nitrates.
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