{"title":"Δ-Cadinene的硫醇和硫乙酸酯衍生物","authors":"Karine Candela, R. Fellous, D. Joulain, R. Faure","doi":"10.1080/02786110210631","DOIUrl":null,"url":null,"abstract":"Photochemical thioacetylation of (s−)- i -cadinene 1 afforded 5-acetylthio-cadinene 1a which was further reduced into 5-mercapto-cadinene 1b in good yield (80%). Thioepoxydation of trans -1,10-cadinene oxide 1c , prepared from m -CPBA oxidation of 1 , was also investigated. Structural determination of these derivatives was achieved by one- and two dimensional NMR spectroscopy.","PeriodicalId":22122,"journal":{"name":"Sulfur Letters","volume":"22 1","pages":"29 - 36"},"PeriodicalIF":0.0000,"publicationDate":"2002-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Thiol and Thioacetate Derivatives of Δ-Cadinene\",\"authors\":\"Karine Candela, R. Fellous, D. Joulain, R. Faure\",\"doi\":\"10.1080/02786110210631\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Photochemical thioacetylation of (s−)- i -cadinene 1 afforded 5-acetylthio-cadinene 1a which was further reduced into 5-mercapto-cadinene 1b in good yield (80%). Thioepoxydation of trans -1,10-cadinene oxide 1c , prepared from m -CPBA oxidation of 1 , was also investigated. Structural determination of these derivatives was achieved by one- and two dimensional NMR spectroscopy.\",\"PeriodicalId\":22122,\"journal\":{\"name\":\"Sulfur Letters\",\"volume\":\"22 1\",\"pages\":\"29 - 36\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Sulfur Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/02786110210631\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sulfur Letters","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/02786110210631","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
摘要
(s−)- i -cadinene 1的光化学硫乙酰化得到5-乙酰基硫代cadinene 1a，进一步还原为5-巯基cadinene 1b，收率很高(80%)。研究了以m -CPBA氧化1制备的反式-1,10-二苯二烯氧化物1c的硫代环氧化反应。这些衍生物的结构测定是通过一维和二维核磁共振波谱实现的。
Photochemical thioacetylation of (s−)- i -cadinene 1 afforded 5-acetylthio-cadinene 1a which was further reduced into 5-mercapto-cadinene 1b in good yield (80%). Thioepoxydation of trans -1,10-cadinene oxide 1c , prepared from m -CPBA oxidation of 1 , was also investigated. Structural determination of these derivatives was achieved by one- and two dimensional NMR spectroscopy.
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