{"title":"不饱和聚合物的过氧化氢环氧化反应","authors":"X. Jian, A. S. Hay","doi":"10.1002/POL.1990.140280903","DOIUrl":null,"url":null,"abstract":"Various unsaturated polymers (SBR, SBS, EPDM rubber and an isoprene-isobutylene copolymer) are epoxidized with good yields using hydrogen peroxide as oxidant and a quaternary ammonium tetrakis(diperoxotungsto)-phosphate(3-) as catalyst","PeriodicalId":16874,"journal":{"name":"Journal of Polymer Science: Polymer Letters Edition","volume":"32 1","pages":"285-288"},"PeriodicalIF":0.0000,"publicationDate":"1990-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"21","resultStr":"{\"title\":\"Epoxidation of unsaturated polymers with hydrogen peroxide\",\"authors\":\"X. Jian, A. S. Hay\",\"doi\":\"10.1002/POL.1990.140280903\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Various unsaturated polymers (SBR, SBS, EPDM rubber and an isoprene-isobutylene copolymer) are epoxidized with good yields using hydrogen peroxide as oxidant and a quaternary ammonium tetrakis(diperoxotungsto)-phosphate(3-) as catalyst\",\"PeriodicalId\":16874,\"journal\":{\"name\":\"Journal of Polymer Science: Polymer Letters Edition\",\"volume\":\"32 1\",\"pages\":\"285-288\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1990-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"21\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Science: Polymer Letters Edition\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/POL.1990.140280903\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Science: Polymer Letters Edition","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/POL.1990.140280903","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Epoxidation of unsaturated polymers with hydrogen peroxide
Various unsaturated polymers (SBR, SBS, EPDM rubber and an isoprene-isobutylene copolymer) are epoxidized with good yields using hydrogen peroxide as oxidant and a quaternary ammonium tetrakis(diperoxotungsto)-phosphate(3-) as catalyst