基于自组装单层界面工程的高整流率聚合物二极管整流器

Khaoula Ferchichi, Sébastien Pecqueur, D. Guérin, R. Bourguiga, K. Lmimouni
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引用次数: 5

摘要

在这项工作中,我们在刚性和柔性衬底上展示了P3HT(聚3-己基噻吩)有机整流二极管,整流比高达106。这种性能是通过自组装的2,3,4,5,6-五氟苯乙醇(PFBT)单层调节金的功函数来实现的。在柔性纸衬底上制造的二极管在弯曲测试中显示出非常好的电稳定性,频率响应估计在20 MHz以上,足以用于射频识别(RFID)应用。这也表明,这种二极管的低工作电压可以是一个真正的优势,用于整流天线的能量收集系统。仿真结果表明,将二极管电容减小到几个pF,串联电阻减小到几百欧姆,可以在GSM和Wi-Fi频率下使用。在这种情况下,整流天线产生的直流电压最高可达1v。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
High Rectification Ratio in Polymer Diode Rectifier through Interface Engineering with Self-Assembled Monolayer
In this work, we demonstrate P3HT (poly 3-hexylthiophene) organic rectifier diode both in rigid and flexible substrate with a rectification ratio up to 106. This performance has been achieved through tuning the work function of gold with a self-assembled monolayer of 2,3,4,5,6-pentafluorobenzenethiol (PFBT). The diode fabricated on flexible paper substrate shows a very good electrical stability under bending tests and the frequency response is estimated at more than 20 MHz which is sufficient for radio frequency identification (RFID) applications. It is also shown that the low operating voltage of this diode can be a real advantage for use in a rectenna for energy harvesting systems. Simulations of the diode structure show that it can be used at GSM and Wi-Fi frequencies if the diode capacitance is reduced to a few pF and its series resistance to a few hundred ohms. Under these conditions, the DC voltages generated by the rectenna can reach a value up to 1 V.
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