α-磺基自由基的断裂:有机合成的通用过程

Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry Pub Date : 2001-07-01 DOI:10.1016/S1387-1609(01)01270-1

Frédérique Bertrand , Frédéric Le Guyader , Lucia Liguori , Gilles Ouvry , Béatrice Quiclet-Sire , Stéphanie Seguin , Samir Z. Zard

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引用次数: 9

摘要

脂肪族自由基对二氧化硫的可逆加成可用于设计各种无锡链式反应。这篇简短的综述总结了一些可能性，即自由基烯丙基化、乙烯基化、炔基化和各种底物的叠氮化。

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α-Scission of sulfonyl radicals: a versatile process for organic synthesis

The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates.

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Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry

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