非对称方烷前体含吡咯基半方烷在水中的简易合成

Compounds Pub Date : 2022-12-28 DOI:10.3390/compounds3010002
Daniel D. Ta, Jeanne M. Favret, S. Dzyuba
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引用次数: 0

摘要

在水中,方酸与吡咯(如3-乙基-2,4-二甲基吡咯和1,2,5-三甲基吡咯)之间的一步反应可以高产地生成相应的2-吡咯基和3-吡咯基半隔离烷。这些半隔离物可作为合成各种不对称含吡咯的方卡因染料的有用前体。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Facile Synthesis of Pyrrolyl-Containing Semisquaraines in Water as Precursors for Non-Symmetric Squaraines
One-step reactions between squaric acid and pyrroles, such as 3-ethyl-2,4-dimethyl-pyrrole and 1,2,5-trimethylpyrrole, in water provide the corresponding pyrrol-2-yl- and pyrrol-3-yl-containing semisquaraines in high yields. These semisquaraines serve as useful precursors for the synthesis of various non-symmetric pyrrole-containing squaraine dyes.
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CiteScore
2.30
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