{"title":"VPI-5和AlPO4-8包封Co(saloph)配合物的表征","authors":"Man-Hyoung Ryoo, Hakze Chon","doi":"10.1016/S0927-6513(96)00121-6","DOIUrl":null,"url":null,"abstract":"<div><p>Co(II)saloph (<em>N, N</em>-bis(salicylidene)-1,2-phenylenediamino-cobalt (II)) was encapsulated into VPI-5 and AlPO<sub>4</sub>-8. Aluminophosphate-hosted cobalt complexes were obtained by impregnating VPI-5 with Co(saloph). Co(saloph) encapsulated into AlPO<sub>4</sub>-8 was obtained by the structural transformation of VPI-5 occluding Co(saloph) into AlPO<sub>4</sub>-8. These complexes were characterized by XRD, and IR, <sup>31</sup>P NMR and UV-VIS-NIR spectroscopy. The encapsulated complexes do not undergo any significant structural distortions in either case. As the amount of loaded Co(saloph) increases, five-coordinated complexes are formed in VPI-5, but not in AlPO<sub>4</sub>-8.</p></div>","PeriodicalId":100926,"journal":{"name":"Microporous Materials","volume":"10 1","pages":"Pages 35-40"},"PeriodicalIF":0.0000,"publicationDate":"1997-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0927-6513(96)00121-6","citationCount":"4","resultStr":"{\"title\":\"The characterization of Co(saloph) complexes encapsulated into VPI-5 and AlPO4-8\",\"authors\":\"Man-Hyoung Ryoo, Hakze Chon\",\"doi\":\"10.1016/S0927-6513(96)00121-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Co(II)saloph (<em>N, N</em>-bis(salicylidene)-1,2-phenylenediamino-cobalt (II)) was encapsulated into VPI-5 and AlPO<sub>4</sub>-8. Aluminophosphate-hosted cobalt complexes were obtained by impregnating VPI-5 with Co(saloph). Co(saloph) encapsulated into AlPO<sub>4</sub>-8 was obtained by the structural transformation of VPI-5 occluding Co(saloph) into AlPO<sub>4</sub>-8. These complexes were characterized by XRD, and IR, <sup>31</sup>P NMR and UV-VIS-NIR spectroscopy. The encapsulated complexes do not undergo any significant structural distortions in either case. As the amount of loaded Co(saloph) increases, five-coordinated complexes are formed in VPI-5, but not in AlPO<sub>4</sub>-8.</p></div>\",\"PeriodicalId\":100926,\"journal\":{\"name\":\"Microporous Materials\",\"volume\":\"10 1\",\"pages\":\"Pages 35-40\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1997-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0927-6513(96)00121-6\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Microporous Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927651396001216\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microporous Materials","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927651396001216","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The characterization of Co(saloph) complexes encapsulated into VPI-5 and AlPO4-8
Co(II)saloph (N, N-bis(salicylidene)-1,2-phenylenediamino-cobalt (II)) was encapsulated into VPI-5 and AlPO4-8. Aluminophosphate-hosted cobalt complexes were obtained by impregnating VPI-5 with Co(saloph). Co(saloph) encapsulated into AlPO4-8 was obtained by the structural transformation of VPI-5 occluding Co(saloph) into AlPO4-8. These complexes were characterized by XRD, and IR, 31P NMR and UV-VIS-NIR spectroscopy. The encapsulated complexes do not undergo any significant structural distortions in either case. As the amount of loaded Co(saloph) increases, five-coordinated complexes are formed in VPI-5, but not in AlPO4-8.
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