利用椭圆红草根茎水提物合成氧化铜纳米颗粒光催化降解亚甲基蓝

Sabita Shrestha, Gagan Shrestha
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引用次数: 1

摘要

本文报道了一种经济、环保的合成CuO纳米粒子(CuO NPs)的方法,该方法以椭圆红草根茎提取物为原料,用于光催化降解亚甲基蓝。萃取物中的生物分子作为还原剂和稳定剂对氧化铜NPs的合成起作用。采用紫外可见分光光度计、XRD和FT-IR等分析仪器对合成的纳米颗粒进行了表征。595 nm处的吸光度表明形成了CuO NPs,在400℃退火4小时后氧化形成CuO NPs,在265 nm处吸光度最大。XRD分析证实了结晶结构纳米颗粒的形成,没有任何杂质。通过Debye-Scherrer方程计算得到了粒径分别为4.8nm和5.7 nm的纳米颗粒。红外光谱证实了各种生物活性成分的存在,这些活性成分起着还原剂和稳定剂的作用。此外,还研究了CuO纳米粒子在日光下对亚甲基蓝的光催化降解活性。用紫外可见分光光度计测定了催化剂的催化活性。结果表明,该染料在日光照射下逐渐降解。本研究强调了氧化铜纳米粒子在染料光催化降解中的应用,并将其推广到废水处理中。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Biogenic synthesis of copper oxide nanoparticles using aqueous rhizome extract of Rubus ellipticus for photocatalytic degradation of methylene blue
In this paper, we have reported the synthesis of CuO nanoparticles (CuO NPs) by cost effectively and environmental friendly method using the rhizome extract of Rubus ellipticusfor photocatalytic degradation of methylene blue. The biomolecules present in the extract acts as reducing agent and stabilizer for the synthesis of CuO NPs. The synthesized nanoparticles were characterized by using the different analytical instrument like UV-Visible spectrophotometer, XRD and FT-IR. The absorbance at 595 nm indicates the formation of CuO NPs which on annealing at 400°C for four hours oxidizes and forms CuO NPs which shows maximum absorbance at 265 nm. XRD analysis confirms the formation of crystalline structured nanoparticles without any impurity. So formed nanoparticles were found to be of size 4.8nm and 5.7 nm which was calculated by using Debye-Scherrer equation. The FTIR confirms the presence of various bioactive components, which acts as reducers and stabilizer. In addition, the photocatalytic degradation activity of the CuO NPs was studied for the degradation of the methylene blue in presence of sunlight. The catalytic activity was monitored using the UV-Visible spectrophotometer. It was found that the dye gradually degrade sunlight irradiation. This study highlights the application of CuO NPs for photocatalytic degradation of dye which can be extended for the waste water treatment.
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