用简单共沉淀法合成的钕铁氧体纳米材料的光学和磁性能

P. Duyen, A. T. Nguyen
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引用次数: 2

摘要

本文以5% NaOH为沉淀剂,在热水中水解Nd (III)和Fe (III)阳离子,采用简单共沉淀法成功合成了粒径为20 ~ 40 nm的正铁氧体NdFeO3纳米材料。将制备的粉末分别在700、800、900℃下煅烧1小时,生成单相NdFeO3。室温下紫外可见光谱在紫外可见区(l = 200-400 nm和400-600 nm)有较强的吸收,带隙能较小(Eg = 2.2÷2.5 eV)。制备的NdFeO3纳米材料具有高矫顽力(Hc = 600 ~ 1600 Oe)的硬铁磁性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optical and magnetic properties of orthoferrite NdFeO3 nanomaterials synthesized by simple co-precipitation method
In this work, orthoferrite NdFeO3 nanomaterials with particle sizes 20-40 nm have been successfully synthesized via a simple co-precipitation method through the hydrolysis of Nd (III) and Fe (III) cations in hot water with 5% NaOH as a precipitating agent. Single-phase NdFeO3 was generated after calcination of the as-prepared powder at 700, 800, and 900 °C for 1 hour. The UV-Vis spectra at room temperature presented strong absorption in the UV-Vis regions (l = 200–400 nm and 400–600 nm) with small band gap energy (Eg = 2.2÷2.5 eV). The obtained NdFeO3 nanomaterials exhibited a hard ferromagnetic behavior with high coercivity (Hc = 600–1600 Oe).
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