Quality of water from shallow wells in the rice-growing area in southwestern Louisiana, 1999 through 2001

In 1999-2001, the U.S. Geological Survey installed and sampled 27 shallow wells in the ricegrowing area in southwestern Louisiana as part of the Acadian-Pontchartrain Study Unit of the National WaterQuality Assessment Program. The purpose of this report is to describe the quality of water from shallow wells in the rice-growing area and to relate that water quality to natural and anthropogenic activities, particularly rice agriculture. Ground-water samples were analyzed for general ground-water properties and about 150 waterquality constituents, including major inorganic ions, trace elements, nutrients, dissolved organic carbon (DOC), pesticides, radon, chlorofluorocarbons, and selected stable isotopes. Dissolved-solids concentrations for 17 wells exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter (mg/L) for drinking water. Concentrations for major inorganic ions, trace elements, and pesticides generally were less than the maximum contaminant levels for drinking water. Two major inorganic ions, sulfate and chloride, and two trace elements, iron and manganese, had concentrations that were greater than the secondary maximum contaminant levels. Three nutrient concentrations were greater than 2 mg/L, a level that might indicate contamination from human activities, and one nutrient concentration (that for nitrite plus nitrate as nitrogen) was greater than the maximum contaminant level of 10 mg/L for drinking water. The median concentration for DOC was 0.5 mg/L, indicating naturally-occurring DOC conditions in the study area. Thirteen pesticides and 7 pesticide degradation products were detected in 14 of the 27 wells sampled. Bentazon, 2,4-D, and molinate (three rice herbicides) were detected in water from four, one, and one wells, respectively, and malathion (a rice insecticide) was detected in water from one well. Low-level concentrations and few detections of nutrients and pesticides indicated that ground-water quality was affected slightly by anthropogenic activities. Quality-control samples, including field blanks, replicates, and spikes, indicated no bias in ground-water data from collection or analysis. Radon concentrations for 22 of the 24 wells sampled were at or greater than the U.S. Environmental Protection Agency proposed maximum contaminant level of 300 picocuries per liter. Chlorofluorocarbon concentrations in selected wells indicated the apparent ages of the ground water varied with depth and water level and ranged from about 17 to 49 years. The stable isotopes of hydrogen and oxygen in water molecules indicated the origin of ground water in the study area was rainwater that originated near the study area and that few geochemical or physical processes influenced the stable isotopic composition of the shallow ground water. The Spearman rank correlation was used to determine whether significant correlations existed between physical properties, selected chemical constituents, the number of pesticides detected, and the apparent age of water. The depth to ground water was positively correlated to the well depth and inversely correlated to dissolved solids and other constituents, such as radon, indicating the ground water was under unconfined or semiconfined conditions and more dilute with increasing depth. As the depth to ground water increased, the concentrations of dissolved solids and other constituents decreased, possibly because the deeper sands had a greater transmittal of ground water, which, over time, would flush out, or dilute, the concentrations of dissolved solids in the natural sediments. The apparent age of water was correlated inversely with nitrite plus nitrate concentration, indicating that as the apparent age increased, the nitrite plus nitrate concentration decreased. No significant correlations existed between the number of pesticides detected and any of the physical or chemical properties of the ground water.