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4-磺酰基吡啶与格氏试剂的直接偶联

Journal of Chemical Research-s Pub Date : 2022-03-01 DOI:10.1177/17475198221103502
Liu-Yi Song, Mengli Chen, Jian Wang, Jinghan Li
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引用次数: 1

摘要

通过磺酰基吡啶与格氏试剂的偶联，建立了烷基磺酰基吡啶和芳基磺酰基吡啶的直接合成方法。该方案通过无催化剂和无氧化剂的偶联磺酰基吡啶作为底物，通过奇奇巴宾型反应机制进行。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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A straightforward coupling of 4-sulfonylpyridines with Grignard reagents
A straightforward synthesis of alkyl-sulfonylpyridines and aryl-sulfonylpyridines is developed by coupling of sulfonylpyridines with the Grignard reagents. The protocol proceeds through a catalyst- and oxidant-free coupling of sulfonylpyridines as substrates via a Chichibabin-type reaction mechanism.
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来源期刊
Journal of Chemical Research-s
Journal of Chemical Research-s 化学科学, 有机化学, 有机合成
自引率
0.00%
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审稿时长
1 months
期刊介绍： The Journal of Chemical Research is a peer reviewed journal that publishes full-length review and research papers in all branches of experimental chemistry. The journal fills a niche by also publishing short papers, a format which favours particular types of work, e.g. the scope of new reagents or methodology, and the elucidation of the structure of novel compounds. Though welcome, short papers should not result in fragmentation of publication, they should describe a completed piece of work. The Journal is not intended as a vehicle for preliminary publications. The work must meet all the normal criteria for acceptance as regards scientific standards. Papers that contain extensive biological results or material relating to other areas of science may be diverted to more appropriate specialist journals. Areas of coverage include: Organic Chemistry; Inorganic Chemistry; Materials Chemistry; Crystallography; Computational Chemistry.
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