基于2-氨基对苯二甲酸和2,6-双(1-咪唑)吡啶的新型Mn(II)配位聚合物:合成、结构和发光性能

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-19 DOI:10.1080/15533174.2015.1137072

Qifeng Liu, Wei Liu

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引用次数: 2

摘要

通过MnCl2、NH2-H2pbc和impy的溶剂热反应合成了一种新的Mn(II)配位聚合物[Mn(impy)(NH2-pbc)]n (1 NH2-H2pbc = 2-氨基对苯二甲酸，impy = 2,6-双(1-咪唑)吡啶)。单x射线结构分析表明，化合物1具有二维层状结构，这些二维层状结构通过弱范德华相互作用进一步堆叠成三维超分子框架。此外，还研究了化合物1和自由隐含配体在室温下的发光特性。

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A New Mn(II) Coordination Polymer Based on Mixed 2-Aminoterephthalic Acid and 2,6-Bis(1-imdazoly)pyridine Ligands: Synthesis, Structure, and Luminescent Property

A new Mn(II) coordination polymer, namely [Mn(impy)(NH2-pbc)]n (1 NH2-H2pbc = 2-aminoterephthalic acid, impy = 2,6-bis(1-imdazoly)pyridine), has been synthesized through solvothermal reactions of MnCl2, NH2-H2pbc and impy. Single X-ray structural analysis reveals that compound 1 features a 2D layered structure, and these 2D sheets are further stacked into a 3D supramolecular framework via weak van der Waals interactions. In addition, the luminescent properties of compound 1 and free impy ligand were also investigated at room temperature.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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审稿时长

5 months