{"title":"不稳定的中间体。LXXXII一部分。γ辐照碱金属卤化物冷冻水溶液中Br2 -、I2 -、BrOH -和IOH -的电子自旋共振谱","authors":"I. Marov, M. Symons","doi":"10.1039/J19710000201","DOIUrl":null,"url":null,"abstract":"Exposure of aqueous solutions of alkali-metal bromides or iodides to 60Co γ-rays at 77 K gave hydroxyl radicals, Br2– or I2–, and species identified as BrOH– or IOH–. The resulting magnetic parameters are compared with those for VK centres in alkali halide crystals, and with CIOH– in strontium chloride hexahydrate. Argentic and mercuric iodide complexes in frozen aqueous solution gave only I2– under these conditions.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"12","resultStr":"{\"title\":\"Unstable intermediates. Part LXXXII. Electron spin resonance spectra of the species Br2–, I2–, BrOH–, and IOH– in γ-irradiated frozen aqueous solutions of alkali-metal halides\",\"authors\":\"I. Marov, M. Symons\",\"doi\":\"10.1039/J19710000201\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Exposure of aqueous solutions of alkali-metal bromides or iodides to 60Co γ-rays at 77 K gave hydroxyl radicals, Br2– or I2–, and species identified as BrOH– or IOH–. The resulting magnetic parameters are compared with those for VK centres in alkali halide crystals, and with CIOH– in strontium chloride hexahydrate. Argentic and mercuric iodide complexes in frozen aqueous solution gave only I2– under these conditions.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710000201\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710000201","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Unstable intermediates. Part LXXXII. Electron spin resonance spectra of the species Br2–, I2–, BrOH–, and IOH– in γ-irradiated frozen aqueous solutions of alkali-metal halides
Exposure of aqueous solutions of alkali-metal bromides or iodides to 60Co γ-rays at 77 K gave hydroxyl radicals, Br2– or I2–, and species identified as BrOH– or IOH–. The resulting magnetic parameters are compared with those for VK centres in alkali halide crystals, and with CIOH– in strontium chloride hexahydrate. Argentic and mercuric iodide complexes in frozen aqueous solution gave only I2– under these conditions.
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