卤化物熔体比电导率与碱金属比电导率的关系

I. Garkushin, O. Lavrenteva, Y. Andreeva
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引用次数: 0

摘要

本文分析了各碱金属卤化物熔体(MHal) (M - Li, Na, K, Rb, Cs, Fr;Hal - F, Cl, Br, I)和碱金属熔体在温度(Тпл + n) (Tпл -熔化温度K;n = 5, 10, 50, 75, 100, 150, 200°(MHal和金属的熔融温度)和碱金属在标准温度下的比电导率,使用m.h。Karapetyans的比较方法。属性æ(MHal при Тпл+n) = f(æ(MHal при Тпл+5)), æ(FrHalТпл+n) = f(æ(FrHalТпл+5°))的关系在“property-property”坐标中描述。对采用上述方法得到的卤化钫熔体的比电导率值进行了比较分析。给出了由熔融金属的电导率计算熔盐电导率的可能性。结果表明,可以用公式æ(MHal)0.5 = a + æ(M)1.5计算卤化钫熔体的比电导率。用各种方程计算比电导率,结果表明所得数值具有一致性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Relationship of the s1-elements halogenides melts specific electric conductivity with alkali metals specific electric conductivity
The paper presents an analytical description of the relationship of the specific electrical conductivity æ of individual alkali metals haloganides melts (MHal) (M – Li, Na, K, Rb, Cs, Fr; Hal – F, Cl, Br, I) and the specific electrical conductivity æ(M) of alkali metal melts for temperatures (Тпл + n) (Tпл – melting temperature K; n = 5, 10, 50, 75, 100, 150, 200° higher melting temperatures of MHal and metals) and the specific electrical conductivity of alkali metals at standard temperature using M.Kh. Karapetyans comparative methods. The relationship of properties æ(MHal при Тпл+n) = f(æ(MHal при Тпл+5)), æ(FrHalТпл+n) = f(æ(FrHalТпл+5°)) is described in the "property-property" coordinates. A comparative analysis of the specific electrical conductivity values of francium haloganides melts obtained by the proposed methods was carried out. The possibility of calculating the electrical conductivity of molten salts from the electrical conductivity of molten metals is shown. It is shown that the equation æ(MHal)0.5 = a + bæ(M)1.5 can be used to calculate the specific electrical conductivity of francium haloganides melts. The calculation of the specific electrical conductivity using various equations shows the consistency of the numerical values obtained.
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