{"title":"不饱和脂肪酸衍生物中乙基乙酯的加成","authors":"A. Behr, M. Fiene","doi":"10.1002/(SICI)1521-4133(199906)101:6<199::AID-LIPI199>3.0.CO;2-4","DOIUrl":null,"url":null,"abstract":"The addition of glyoxylic acid ethyl ester to unsaturated fatty acid derivatives occurs with a maximum yield of 89%. The products are the corresponding 1:1-adducts. Temperature, reaction time, stoichiometry, and the concentration of the fatty acid derivative were investigated and optimized. A maximum yield was obtained with a fourfold excess of oleic acid ethyl ester, a reaction temperature of 200°C, a reaction time of 24 h, and an oleic acid ethyl ester concentration of 1.3 mol/l.","PeriodicalId":12304,"journal":{"name":"Fett-lipid","volume":"24 1","pages":"199-202"},"PeriodicalIF":0.0000,"publicationDate":"1999-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Addition of glyoxylic acid ethyl ester to unsaturated fatty acid derivatives\",\"authors\":\"A. Behr, M. Fiene\",\"doi\":\"10.1002/(SICI)1521-4133(199906)101:6<199::AID-LIPI199>3.0.CO;2-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The addition of glyoxylic acid ethyl ester to unsaturated fatty acid derivatives occurs with a maximum yield of 89%. The products are the corresponding 1:1-adducts. Temperature, reaction time, stoichiometry, and the concentration of the fatty acid derivative were investigated and optimized. A maximum yield was obtained with a fourfold excess of oleic acid ethyl ester, a reaction temperature of 200°C, a reaction time of 24 h, and an oleic acid ethyl ester concentration of 1.3 mol/l.\",\"PeriodicalId\":12304,\"journal\":{\"name\":\"Fett-lipid\",\"volume\":\"24 1\",\"pages\":\"199-202\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1999-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fett-lipid\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/(SICI)1521-4133(199906)101:6<199::AID-LIPI199>3.0.CO;2-4\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fett-lipid","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/(SICI)1521-4133(199906)101:6<199::AID-LIPI199>3.0.CO;2-4","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Addition of glyoxylic acid ethyl ester to unsaturated fatty acid derivatives
The addition of glyoxylic acid ethyl ester to unsaturated fatty acid derivatives occurs with a maximum yield of 89%. The products are the corresponding 1:1-adducts. Temperature, reaction time, stoichiometry, and the concentration of the fatty acid derivative were investigated and optimized. A maximum yield was obtained with a fourfold excess of oleic acid ethyl ester, a reaction temperature of 200°C, a reaction time of 24 h, and an oleic acid ethyl ester concentration of 1.3 mol/l.
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