{"title":"对硝基苯酚供体体系中质子转移和氢键的光谱研究","authors":"A.S.N. Murthy, A. Ram Reddy","doi":"10.1016/0378-4487(82)80006-X","DOIUrl":null,"url":null,"abstract":"<div><p>The interaction of p-nitrophenol with several electron-donors has been studied in aprotic and protic solvents by electronic absorption spectroscopy. The equilibrium data for different kinds of equilibria in 1,2-dichloroethane, n-butanol and acetonitrile have been obtained and discussed. The strong hydrogen bonding interaction between p-nitrophenol and a variety of electron donors has been investigated in heptane by electronic absorption spectroscopy. The interesting correlations obtained in terms of Mulliken's charge transfer model have been examined and extended in many cases.</p></div>","PeriodicalId":100049,"journal":{"name":"Advances in Molecular Relaxation and Interaction Processes","volume":"22 3","pages":"Pages 199-221"},"PeriodicalIF":0.0000,"publicationDate":"1982-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-4487(82)80006-X","citationCount":"6","resultStr":"{\"title\":\"Spectroscopic studies on proton transfer and hydrogen bonding in p-nitrophenol-donor systems\",\"authors\":\"A.S.N. Murthy, A. Ram Reddy\",\"doi\":\"10.1016/0378-4487(82)80006-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The interaction of p-nitrophenol with several electron-donors has been studied in aprotic and protic solvents by electronic absorption spectroscopy. The equilibrium data for different kinds of equilibria in 1,2-dichloroethane, n-butanol and acetonitrile have been obtained and discussed. The strong hydrogen bonding interaction between p-nitrophenol and a variety of electron donors has been investigated in heptane by electronic absorption spectroscopy. The interesting correlations obtained in terms of Mulliken's charge transfer model have been examined and extended in many cases.</p></div>\",\"PeriodicalId\":100049,\"journal\":{\"name\":\"Advances in Molecular Relaxation and Interaction Processes\",\"volume\":\"22 3\",\"pages\":\"Pages 199-221\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1982-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0378-4487(82)80006-X\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Molecular Relaxation and Interaction Processes\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/037844878280006X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Molecular Relaxation and Interaction Processes","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/037844878280006X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Spectroscopic studies on proton transfer and hydrogen bonding in p-nitrophenol-donor systems
The interaction of p-nitrophenol with several electron-donors has been studied in aprotic and protic solvents by electronic absorption spectroscopy. The equilibrium data for different kinds of equilibria in 1,2-dichloroethane, n-butanol and acetonitrile have been obtained and discussed. The strong hydrogen bonding interaction between p-nitrophenol and a variety of electron donors has been investigated in heptane by electronic absorption spectroscopy. The interesting correlations obtained in terms of Mulliken's charge transfer model have been examined and extended in many cases.