磁枇杷籽去除水溶液中甲基蓝的研究

Emel Moral, Fethiye Göde, Okan Bayram
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摘要

目的:以枇杷种子为原料制备生物炭和磁性生物炭。所得生物炭用于去除水溶液中的甲基蓝。研究设计:考察吸附剂投加量、pH、初始甲基蓝浓度、时间和温度对吸附过程的影响。学习地点和时间:莱曼德米雷尔大学应用与自然科学研究生院化学系,2022年2月至2023年2月。方法:采用间歇式吸附法,是一种简便、常用的去除水中染料的方法。利用红外光谱(FTIR)、BET分析对改性枇杷种子进行了表征。从动力学、平衡和热力学等方面对吸附过程进行了研究。结果:生物炭的最大吸附量为31.746 mg/g,磁性生物炭的最大吸附量为67.568 mg/g。根据动力学数据,吸附速率为准二级。根据热力学数据,负ΔG值表明甲基蓝的吸附是自发发生的。根据负ΔH值,吸附过程为放热。考察吸附等温线,发现枇杷生物炭和改性枇杷生物炭均符合Langmuir吸附等温线。结论:改性枇杷籽可用于去除水溶液中的甲基蓝染料。所使用的吸附剂可以用不同的化学物质进行改性,以增加吸附能力,并有助于文献。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Removal of Methyl Blue from Aqueous Solution Using Magnetic Loquat (Eriobotrya japonica) Seed
Aims: In this study, biochar and magnetic biochar were obtained from loquat seeds. The obtained biochars were used to remove methyl blue from the aqueous solution. Study Design: The effects of adsorbent substance dosage, pH, initial methyl blue concentration, time and temperature on the adsorption process were investigated. Place and Duration of Study: Department of Chemistry, Graduate School of Applied and Natural Sciences, Süleyman Demirel University, between February 2022 and February 2023. Methodology: In this study, batch adsorption method, which is an easily applicable and common method, was used to remove dye from aqueous media. Modified loquat seeds were characterized by FTIR, BET analysis. The adsorption process was investigated in terms of kinetics, equilibrium and thermodynamics. Results: The maximum adsorption capacity was 31.746 mg/g for biochar and 67.568 mg/g for magnetic biochar. According to the kinetic data, the adsorption rate is pseudo-second-order. According to the thermodynamic data, negative ΔG values indicated that adsorption of methyl blue occurred spontaneously. According to negative ΔH values, the adsorption process was exothermic. When the adsorption isotherms were examined, it was seen that loquat biochar and modified loquat biochar were suitable for the Langmuir adsorption isotherm. Conclusion: Modified loquat seeds can be used to remove methyl blue dye from aqueous solutions. The adsorbents used can be modified with different chemicals to increase the adsorption capacity and contribute to the literature.
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