基于3,5-二(吡啶-2-基)-4-氨基-1,2,4-三唑的Cd(II)， Ag(I)配合物的合成、晶体结构和荧光性质

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-07-02 DOI:10.1080/15533174.2015.1004417

J. Qin, Na Lei, H. Ding, Ya-Ping Liu, Yong-Peng Xu, S. Qian

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引用次数: 3

摘要

得到了两个d10配合物[Cd(abt)I2(H2O)](1)和[Ag2(abt)2]·2(CF3SO3) (2)， (abt = 4-氨基-3,5-双(吡啶-2-基)-1,2,4-三唑)，并通过红外光谱、元素分析和x射线衍射单晶分析对其进行了表征。配合物1为单核结构，Cd(II)中心为5配位;配合物2为双核结构，Ag(I)中心为4配位。研究了1、2和abt在室温下的固态荧光光谱。

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Syntheses, Crystal Structures, and Fluorescence Properties of Cd(II), Ag(I) Complexes Based on 3,5-bis(pyridin-2-yl)-4-amino-1,2,4-triazole

Two d10 complexes [Cd(abt)I2(H2O)] (1) and [Ag2(abt)2]·2(CF3SO3) (2), (abt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) have been obtained and characterized by IR, elemental analysis, and X-ray diffraction single-crystal analysis. Complex 1 is mononuclear and Cd(II) center is five coordinated, while complex 2 possesses a dinuclear structure with coordination number 4 for Ag(I) center. Solid-state fluorescence spectra of 1, 2, and abt were investigated at room temperature.

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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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5 months