铂原子上含二苯基膦配体的苯基偏二苯基铂配合物:合成、红外、核磁共振光谱和电化学性质

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY

Journal of Siberian Federal University. Chemistry Pub Date : 2020-09-01 DOI:10.17516/1998-2836-0191

O. S. Chudin, V. V. Verpekin, G. V. Burmakina, Dmitry V. Zimonin, A. Kondrasenko, A. I. Rubaylo

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引用次数: 0

摘要

首次合成了μ-苯基偏二配合物Cp(CO)2RePt(μ-C=CHPh)(PPh2H)(L) [L = PPh3 (1)， P(OPri)3(2)]。研究了它们的红外光谱、核磁共振光谱和氧化还原性能。根据红外、核磁共振光谱数据，提出了它们的分子结构。确定了配合物的氧化还原反应途径

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Phenylvinylidene RePt Complexes Containing Diphenylphosphine Ligands at the Platinum Atom: Synthesis, IR, NMR Spectroscopic and Electrochemical Properties

The μ-phenylvinylidene complexes Cp(CO)2RePt(μ-C=CHPh)(PPh2H)(L) [L = PPh3 (1), P(OPri)3 (2)] were synthesized for the first time. Their IR, NMR spectroscopic and redox properties were studied. Based on IR, NMR spectroscopic data their molecular structures were proposed. The pathways of redox-reactions of the complexes were determined

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来源期刊

Journal of Siberian Federal University. Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.10

自引率

0.00%

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