{"title":"对cl -和对f -苯基马鞭烯的首次合成","authors":"Claudia A Contreras-Celedón, L. Chacón-García","doi":"10.2174/1874095200801020100","DOIUrl":null,"url":null,"abstract":"The first synthesis of 4´-X-phenylverbenene (X = F and Cl) via reaction of myrtenal with 4� -X phenylmagne- sium bromide and Bi(NO3)3 is described. Verbenene is formed due to the electron-withdrawing effect of the 4� - electronegative group, either fluorine or a Cl-Bi complex.","PeriodicalId":23020,"journal":{"name":"The Open Organic Chemistry Journal","volume":"27 1","pages":"100-106"},"PeriodicalIF":0.0000,"publicationDate":"2008-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The First Synthesis of p-Cl- and p-F-Phenylverbenene\",\"authors\":\"Claudia A Contreras-Celedón, L. Chacón-García\",\"doi\":\"10.2174/1874095200801020100\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The first synthesis of 4´-X-phenylverbenene (X = F and Cl) via reaction of myrtenal with 4� -X phenylmagne- sium bromide and Bi(NO3)3 is described. Verbenene is formed due to the electron-withdrawing effect of the 4� - electronegative group, either fluorine or a Cl-Bi complex.\",\"PeriodicalId\":23020,\"journal\":{\"name\":\"The Open Organic Chemistry Journal\",\"volume\":\"27 1\",\"pages\":\"100-106\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-11-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Open Organic Chemistry Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/1874095200801020100\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Organic Chemistry Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1874095200801020100","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The First Synthesis of p-Cl- and p-F-Phenylverbenene
The first synthesis of 4´-X-phenylverbenene (X = F and Cl) via reaction of myrtenal with 4� -X phenylmagne- sium bromide and Bi(NO3)3 is described. Verbenene is formed due to the electron-withdrawing effect of the 4� - electronegative group, either fluorine or a Cl-Bi complex.
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