J.Masełko T. Tłaczala, M. Czerwiński, J. Michałczyk, Z. Sikorski
{"title":"系统中的振荡反应:krebs循环的代谢物- mn2 +-KBrO3-H2SO4","authors":"J.Masełko T. Tłaczala, M. Czerwiński, J. Michałczyk, Z. Sikorski","doi":"10.1016/S0006-3061(00)80136-2","DOIUrl":null,"url":null,"abstract":"<div><p>The appearance of oscillations in the Krebs cycle with metabolites such as oxaloacetic and citric acids has been confirmed experimentally in model systems utilizing Mn<sup>2+</sup> as the catalyst and KBrO<sub>3</sub>/H<sub>2</sub>SO<sub>4</sub> as the oxidant. Oscillations occur over a range of concentrations of substrate. The oscillation period also depends on the metabolite concentration. It has been found that malic acid and oxaloacetic acid constitute a coupled oscillator system. The experiments are discussed in relation to other metabolite cycles.</p></div>","PeriodicalId":9177,"journal":{"name":"Bioinorganic chemistry","volume":"9 6","pages":"Pages 529-536"},"PeriodicalIF":0.0000,"publicationDate":"1978-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0006-3061(00)80136-2","citationCount":"5","resultStr":"{\"title\":\"Oscillation reactions in the system: Metabolites of krebs cycle-Mn2+-KBrO3-H2SO4\",\"authors\":\"J.Masełko T. Tłaczala, M. Czerwiński, J. Michałczyk, Z. Sikorski\",\"doi\":\"10.1016/S0006-3061(00)80136-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The appearance of oscillations in the Krebs cycle with metabolites such as oxaloacetic and citric acids has been confirmed experimentally in model systems utilizing Mn<sup>2+</sup> as the catalyst and KBrO<sub>3</sub>/H<sub>2</sub>SO<sub>4</sub> as the oxidant. Oscillations occur over a range of concentrations of substrate. The oscillation period also depends on the metabolite concentration. It has been found that malic acid and oxaloacetic acid constitute a coupled oscillator system. The experiments are discussed in relation to other metabolite cycles.</p></div>\",\"PeriodicalId\":9177,\"journal\":{\"name\":\"Bioinorganic chemistry\",\"volume\":\"9 6\",\"pages\":\"Pages 529-536\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1978-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0006-3061(00)80136-2\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bioinorganic chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0006306100801362\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bioinorganic chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0006306100801362","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Oscillation reactions in the system: Metabolites of krebs cycle-Mn2+-KBrO3-H2SO4
The appearance of oscillations in the Krebs cycle with metabolites such as oxaloacetic and citric acids has been confirmed experimentally in model systems utilizing Mn2+ as the catalyst and KBrO3/H2SO4 as the oxidant. Oscillations occur over a range of concentrations of substrate. The oscillation period also depends on the metabolite concentration. It has been found that malic acid and oxaloacetic acid constitute a coupled oscillator system. The experiments are discussed in relation to other metabolite cycles.