基于6-(3′，4′-二羧基-苯氧基)间苯二甲酸和4,4′-联吡啶混合配体的新型三节(3,4,6)连接镍(II)配位聚合物

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-16 DOI:10.1080/15533174.2015.1137064

C. Song, Xiaohui Li, Wei Liu, Ziqing Cao, Yuanyuan Ren, Qichao Zhou, Li Zhang

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引用次数: 1

摘要

本文报道了一种新的Ni(II)化合物{Ni2(L)(bipy)2(H2O)2}n (1h4l = 6-(3′，4′-二羧基-苯氧基)间苯二甲酸，bipy = 4,4′-联吡啶)，通过Ni(NO3)2·6H2O、H4L和bipy的溶剂热反应合成。单晶x射线分析表明，化合物1在三斜P-1空间群中结晶，胞元参数为a = 9.8887(6)， b = 9.9884(4)， c = 19.2310(11)， α = 79.187(4)， β = 83.862(5)， γ = 80.708(4)。标题化合物具有三维(3D)框架，可简化为三节(3,4,6)连接的拓扑网络。此外，还研究了化合物1的热性能和发光性能。

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A New Trinodal (3,4,6)-Connected Ni(II) Coordination Polymer Based on the Mixed Ligands of 6-(3′,4′-Dicarboxyl-Phenoxy) Isophthalic Acid and 4,4′-Bipyridine

Reported here is a new Ni(II) compound, namely {Ni2(L)(bipy)2(H2O)2}n (1 H4L = 6-(3′,4′-dicarboxyl-phenoxy)isophthalic acid, bipy = 4,4′-bipyridine), which has been synthesized via the solvothermal reactions of Ni(NO3)2·6H2O, H4L and bipy. Single crystal X-ray analysis reveals that compound 1 crystallizes in triclinic P-1 space group with cell parameters a = 9.8887(6), b = 9.9884(4), c = 19.2310(11), α = 79.187(4), β = 83.862(5), γ = 80.708(4). The title compound features a three-dimensional (3D) framework and can be simplified into a trinodal (3,4,6)-connected topological network. Moreover, the thermal and luminescent properties of compound 1 were also investigated.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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5 months