George Christou , David Collison , C. David Garner , Frank E. Mabbs *
{"title":"类古巴烷簇二聚体[NEt4]3[Fe6M2S8(SPh)6(OMe)3] (M、Mo或W)的自旋交换作用","authors":"George Christou , David Collison , C. David Garner , Frank E. Mabbs *","doi":"10.1016/0020-1650(81)80060-8","DOIUrl":null,"url":null,"abstract":"<div><p>Average magnetic moments, <span><math><mrow><msub><mover><mo>μ</mo><mo>¯</mo></mover><mrow><munder><mo>m</mo><mo>¯</mo></munder></mrow></msub></mrow></math></span>, versus temperature in the range 300−1.8K, and the variation of <span><math><mrow><msub><mover><mo>μ</mo><mo>¯</mo></mover><mrow><munder><mo>m</mo><mo>¯</mo></munder></mrow></msub></mrow></math></span> with applied magnetic field, from 0.125 to 2.0T, are reported for [NEt<sub>4</sub>]<sub>3</sub>[Fe<sub>6</sub>M<sub>2</sub>S<sub>8</sub>(SPh)<sub>6</sub>(OMe)<sub>3</sub>] (M <img> Mo or W). These data have been interpreted in terms of antiferromagnetic spin coupling between the iron atoms within the separate {Fe<sub>3</sub>MS<sub>4</sub>} cubane-like clusters of the anions.</p></div>","PeriodicalId":13630,"journal":{"name":"Inorganic and Nuclear Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-1650(81)80060-8","citationCount":"3","resultStr":"{\"title\":\"Spin-exchange interactions in the cubane-like cluster dimers [NEt4]3[Fe6M2S8(SPh)6(OMe)3] (M Mo or W)\",\"authors\":\"George Christou , David Collison , C. David Garner , Frank E. Mabbs *\",\"doi\":\"10.1016/0020-1650(81)80060-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Average magnetic moments, <span><math><mrow><msub><mover><mo>μ</mo><mo>¯</mo></mover><mrow><munder><mo>m</mo><mo>¯</mo></munder></mrow></msub></mrow></math></span>, versus temperature in the range 300−1.8K, and the variation of <span><math><mrow><msub><mover><mo>μ</mo><mo>¯</mo></mover><mrow><munder><mo>m</mo><mo>¯</mo></munder></mrow></msub></mrow></math></span> with applied magnetic field, from 0.125 to 2.0T, are reported for [NEt<sub>4</sub>]<sub>3</sub>[Fe<sub>6</sub>M<sub>2</sub>S<sub>8</sub>(SPh)<sub>6</sub>(OMe)<sub>3</sub>] (M <img> Mo or W). These data have been interpreted in terms of antiferromagnetic spin coupling between the iron atoms within the separate {Fe<sub>3</sub>MS<sub>4</sub>} cubane-like clusters of the anions.</p></div>\",\"PeriodicalId\":13630,\"journal\":{\"name\":\"Inorganic and Nuclear Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1981-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-1650(81)80060-8\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic and Nuclear Chemistry Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020165081800608\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic and Nuclear Chemistry Letters","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020165081800608","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Spin-exchange interactions in the cubane-like cluster dimers [NEt4]3[Fe6M2S8(SPh)6(OMe)3] (M Mo or W)
Average magnetic moments, , versus temperature in the range 300−1.8K, and the variation of with applied magnetic field, from 0.125 to 2.0T, are reported for [NEt4]3[Fe6M2S8(SPh)6(OMe)3] (M Mo or W). These data have been interpreted in terms of antiferromagnetic spin coupling between the iron atoms within the separate {Fe3MS4} cubane-like clusters of the anions.
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