{"title":"二羰基-π-环戊二烯二氧基[三(正丁基)膦]钼(II)的晶体和分子结构","authors":"R. Fenn, J. Cross","doi":"10.1039/J19710003312","DOIUrl":null,"url":null,"abstract":"The title compound crystallises in the space group P42/n(C4h4), with Z= 8, in a unit cell of dimensions: a=b= 19·704 ± 0·006, c= 11·736 ± 0·008 A. The structure was solved from visually estimated photographic data by the heavy-atom method, and refined to R 11·1% for 938 independent reflections. The molecule has a sandwich-type configuration with the cyclopentadienyl ring on one side of the molybdenum, and the other ligands, which are roughly square planar, lying on the other side. The carbonyls are mutually cis.","PeriodicalId":17321,"journal":{"name":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","volume":"1 1","pages":"3312-3315"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"Crystal and molecular structure of dicarbonyl-π-cyclopentadienyliodo[tri(n-butyl)phosphine]molybdenum(II)\",\"authors\":\"R. Fenn, J. Cross\",\"doi\":\"10.1039/J19710003312\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The title compound crystallises in the space group P42/n(C4h4), with Z= 8, in a unit cell of dimensions: a=b= 19·704 ± 0·006, c= 11·736 ± 0·008 A. The structure was solved from visually estimated photographic data by the heavy-atom method, and refined to R 11·1% for 938 independent reflections. The molecule has a sandwich-type configuration with the cyclopentadienyl ring on one side of the molybdenum, and the other ligands, which are roughly square planar, lying on the other side. The carbonyls are mutually cis.\",\"PeriodicalId\":17321,\"journal\":{\"name\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"volume\":\"1 1\",\"pages\":\"3312-3315\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society A: Inorganic, Physical, Theoretical\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J19710003312\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society A: Inorganic, Physical, Theoretical","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J19710003312","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Crystal and molecular structure of dicarbonyl-π-cyclopentadienyliodo[tri(n-butyl)phosphine]molybdenum(II)
The title compound crystallises in the space group P42/n(C4h4), with Z= 8, in a unit cell of dimensions: a=b= 19·704 ± 0·006, c= 11·736 ± 0·008 A. The structure was solved from visually estimated photographic data by the heavy-atom method, and refined to R 11·1% for 938 independent reflections. The molecule has a sandwich-type configuration with the cyclopentadienyl ring on one side of the molybdenum, and the other ligands, which are roughly square planar, lying on the other side. The carbonyls are mutually cis.
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