硫酸盐还原菌SRB控制及基于风险的SRB严重性排序

J. I. Emmanuel, T. T. Shaapere
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引用次数: 0

摘要

全球每年因钢材腐蚀造成的损失估计为2.5万亿美元(小)。硫酸盐还原菌(SRB)是引起内腐蚀失效的主要细菌之一。目前,国际石油天然气公司(ioc)控制硫酸盐还原菌(SRB)以降低湿处理或未处理原油输送管道或储罐上微生物诱导腐蚀(MIC)风险的方法,是通过批处理或段塞处理,在两个清管器之间注入杀菌剂,或者在没有同时发射多个清管器的在线设施的情况下,通过毛管直接注入。国际上控制SRB的最佳做法是就地杀死细菌,防止下游设备和管道受到污染。为了提高杀灭效果和防止SRB耐药菌株的出现,根据制定方案的腐蚀工程师或腐蚀顾问确定的计划处理频率,交替使用杀菌剂。杀灭时间测试是在现场进行的,以确定浮游细菌的浓度和杀灭时间。然而,除非利用两头猪之间的段塞来最大限度地就地接触SRB,否则通常很难确定无根SRB的杀灭时间。在制定杀菌剂处理方案时,需要考虑的其他参数包括管道的历史数据、混合流速、气油比(GOR)、含水(基础沉积物)和水(BS&W)、管道地形、管道显著因子、最大点蚀率、最大均匀腐蚀率和历史泄漏历史。评估静态设备(储罐或管道)SRB风险的方法因公司而异,并且没有普遍接受的标准来作为最佳和有效处理的基准。此外,在现场监测的SRB (Sessile或plankton)的类型也受到了行业利益相关者和腐蚀从业者的争论。虽然有些作业者只监测水相的浮游生物,但其他作业者则通过安装生物探针和油田水样微生物分析中的浮游生物来监测无根生长。本文介绍了目前的实践,确定了实践中的差距,并提出了基于风险的SRB表征方法,以提高杀菌剂的治疗效果和监测。作者的意图是激发一场辩论,这将导致国际石油和天然气公司(ioc)在杀菌剂处理策略方面的最佳实践的发展。作者认为,使用基于风险的方法改进SRB特征的治疗策略,除了大幅优化成本外,还可以提高治疗效率,达到20%的运营成本和25%的资本支出。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Sulphate Reducing Bacteria SRB Control and Risk Based SRB Severity Ranking
The annual cost of steel corrosion is estimated to be $2,500 billon across the globe (Small). Sulphate Reducing Bacteria (SRB) is one of the most implicated Bacteria in internal corrosion failures worldwide. Currently the method for controlling Sulphate Reducing Bacteria (SRB) by the International Oil and Gas Companies (IOCs) to mitigate the risk of Microbiological Induced Corrosion (MIC) on their wet treated or untreated crude oil transmission pipelines or tanks is by either batch treatment or slug treatment by injecting biocide between two pigs or direct injection through quill in the absence of online facilities for launching multiple pigs simultaneously. The international best practise for the control of SRB is to kill the bacteria in-situ and prevent the contamination of downstream equipment and piping. To increase killing effectiveness and prevent resistant strains of SRB from been developed, biocides are alternated based on planned treatment frequency determine by the corrosion engineer or corrosion consultant that developed the programme. Time to kill test is conducted in the field to determine the concentration and time to kill the planktonic bacteria, however, determining the time to kill for sessile SRB is often difficult to achieve except slug between two pigs is utilised to create maximum contact with SRB in-situ. Other parameters to be considered when developing a biocide treatment program are the historical data of the pipeline, the mixed flow velocity, Gas Oil Ratio (GOR), Water Cut (Base Sediment) and Water (BS&W), Pipeline topography, pipeline significance factor, maximum pitting rate, maximum uniform corrosion rate and historical leak history. The method of assessing the risk due to SRB for static equipment (tanks or pipelines) varies from company to company and there is no universally acceptable standard on what to consider as bench mark for best and effective treatment. In addition, the kind of SRB (Sessile or Planktonic) to be monitored in-situ has also been debated by industry stake holders and corrosion practitioners. Whilst some operators monitor only planktonic in water phase, others monitor sessile growth via installed bio-probes and planktonic from oil field water sample microbiological analysis. This paper present current practise, identify the gaps in the practise and propose risk based approach to SRB characterization to enhance biocide treatment effectiveness and monitoring. It is the intention of the authors to spur a debate that will lead to the development of best practise in biocide treatment strategy by the International Oil and Gas Companies (IOCs). The authors are of the opinion that improving treatment strategy with SRB characterization using risk based approach will result in efficiency of treatment in addition to substantial cost optimisation to the tune of 20% OPEX and 25% CAPEX.
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