{"title":"由棒状颗粒组成的纯β-磷酸三钙颗粒的制备技术","authors":"M. Kamitakahara, R. Fujii, K. Ioku","doi":"10.3363/PRB.26.29","DOIUrl":null,"url":null,"abstract":"Hydrothermal, Phosphate Abstract: Spherical β-tricalcium phosphate (β-TCP) granules composed of rod-shaped particles are expected to be useful as bioresorbable bone substitutes. The β-TCP granules can be prepared by the heat treatment of Ca-deficient hydroxyapatite (HA) granules that are synthesized by hydrothermal treatment of -TCP granules. However, when the Ca/P molar ratio of Ca-deficient HA becomes higher than 1.50, depending on the hydrothermal conditions, not only the β-TCP but also the HA phase appears following heat treatment. To resolve this problem, phosphate ions were incorporated into the Ca-deficient HA granules or monetite was added to decrease the Ca/P molar ratio to less than 1.50 in the starting composition. We revealed that these processes were effective in obtaining the pure -TCP granules composed of rod-shaped particles and thus preventing","PeriodicalId":20022,"journal":{"name":"Phosphorus Research Bulletin","volume":"40 1","pages":"29-32"},"PeriodicalIF":0.0000,"publicationDate":"2012-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"TECHNIQUES FOR PREPARING PURE β-TRICALCIUM PHOSPHATE GRANULES COMPOSED OF ROD-SHAPED PARTICLES\",\"authors\":\"M. Kamitakahara, R. Fujii, K. Ioku\",\"doi\":\"10.3363/PRB.26.29\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Hydrothermal, Phosphate Abstract: Spherical β-tricalcium phosphate (β-TCP) granules composed of rod-shaped particles are expected to be useful as bioresorbable bone substitutes. The β-TCP granules can be prepared by the heat treatment of Ca-deficient hydroxyapatite (HA) granules that are synthesized by hydrothermal treatment of -TCP granules. However, when the Ca/P molar ratio of Ca-deficient HA becomes higher than 1.50, depending on the hydrothermal conditions, not only the β-TCP but also the HA phase appears following heat treatment. To resolve this problem, phosphate ions were incorporated into the Ca-deficient HA granules or monetite was added to decrease the Ca/P molar ratio to less than 1.50 in the starting composition. We revealed that these processes were effective in obtaining the pure -TCP granules composed of rod-shaped particles and thus preventing\",\"PeriodicalId\":20022,\"journal\":{\"name\":\"Phosphorus Research Bulletin\",\"volume\":\"40 1\",\"pages\":\"29-32\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2012-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Phosphorus Research Bulletin\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3363/PRB.26.29\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus Research Bulletin","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3363/PRB.26.29","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
TECHNIQUES FOR PREPARING PURE β-TRICALCIUM PHOSPHATE GRANULES COMPOSED OF ROD-SHAPED PARTICLES
Hydrothermal, Phosphate Abstract: Spherical β-tricalcium phosphate (β-TCP) granules composed of rod-shaped particles are expected to be useful as bioresorbable bone substitutes. The β-TCP granules can be prepared by the heat treatment of Ca-deficient hydroxyapatite (HA) granules that are synthesized by hydrothermal treatment of -TCP granules. However, when the Ca/P molar ratio of Ca-deficient HA becomes higher than 1.50, depending on the hydrothermal conditions, not only the β-TCP but also the HA phase appears following heat treatment. To resolve this problem, phosphate ions were incorporated into the Ca-deficient HA granules or monetite was added to decrease the Ca/P molar ratio to less than 1.50 in the starting composition. We revealed that these processes were effective in obtaining the pure -TCP granules composed of rod-shaped particles and thus preventing