D. Burdinski, F. Birkelbach, M. Gerdan, A. Trautwein, K. Wieghardt, P. Chaudhuri
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引用次数: 8
摘要
金属大环[LCrIIIµ-{(Hdmg)2(dmg)} criil](ClO4)2·MeOH (L = 1,4,7-三甲基-1,4,7-三氮杂环壬烷;dmg = dinaion of dimethylglyxime)，通过一步高产率模板反应合成，并通过x射线晶体学和磁化率测量对其进行了表征。
Self-assembly of a novel 14-membered metallamacrobicycle containing two chromium(III) ions as part of the ring skeleton
A metallamacrocycle, [LCrIIIµ-{(Hdmg)2(dmg)}CrIIIL](ClO4)2·MeOH (L = 1,4,7-trimethyl-1,4,7-triazacyclononane; dmg = dianion of dimethylglyoxime), is synthesized by a one-step high yield template reaction and characterized by X-ray crystallography and magnetic susceptibility measurements.
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